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000453510 1001_ $$0P:(DE-H253)PIP1029767$$aPudza, Inga$$b0$$eCorresponding author
000453510 245__ $$aStudy of the thermochromic phase transition in CuMo$_{1−x}$W$_x$O$_4$ solid solutions at the W L$_3$-edge by resonant X-ray emission spectroscopy
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000453510 520__ $$aPolycrystalline CuMo$_{1-x}$W$_x$O$_4$ solid solutions were studied by resonant X-ray emission spectroscopy (RXES) at the W L$_3$-edge to follow a variation of the tungsten local atomic and electronic structures across thermochromic phase transition as a function of sample composition and temperature. The experimental results were interpreted using ab initio calculations. The crystal-field splitting parameter Delta for the 5d(W)-states was obtained from the analysis of the RXES plane and was used to evaluate the coordination of tungsten atoms. Temperature-dependent RXES measurements were successfully employed to determine the hysteretic behaviour of the structural phase transition between the alpha and gamma phases in CuMo$_{1-x}$W$_x$O$_4$ solid solutions on cooling and heating, even at low (x<0.10) tungsten content. It was found that tungsten ions have octahedral coordination for in the whole studied temperature range (90-420 K), whereas their coordination changes from tetrahedral to octahedral upon cooling for smaller (x<=0.15) tungsten content. Nevertheless, some amount of tungsten ions was found to co-exists in the octahedral environment at room temperature for x<0.15. The obtained results correlate well with the color change in these solid solutions.
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000453510 7001_ $$0P:(DE-H253)PIP1008420$$aKalinko, Aleksandr$$b1$$udesy
000453510 7001_ $$0P:(DE-H253)PIP1031834$$aCintins, Arturs$$b2
000453510 7001_ $$0P:(DE-H253)PIP1009042$$aKuzmin, Aleksejs$$b3$$eCorresponding author
000453510 773__ $$0PERI:(DE-600)2014621-8$$a10.1016/j.actamat.2020.116581$$gVol. 205, p. 116581 -$$p116581 (1-32)$$tActa materialia$$v205$$x1359-6454$$y2021
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