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| Home > Publications database > VIS- VUV spectroscopy of $K_5GdLi_2F_{10}$: Tb, Eu and temperature activated energy transfer from terbium to europium > print |
| Home > Publications database > VIS- VUV spectroscopy of $K_5GdLi_2F_{10}$: Tb, Eu and temperature activated energy transfer from terbium to europium > print |
| 001 | 450368 | ||
| 005 | 20250724175218.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jallcom.2020.157459 |2 doi |
| 024 | 7 | _ | |a 0925-8388 |2 ISSN |
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| 100 | 1 | _ | |a Solarz, Piotr |0 P:(DE-H253)PIP1008995 |b 0 |e Corresponding author |
| 245 | _ | _ | |a VIS- VUV spectroscopy of $K_5GdLi_2F_{10}$: Tb, Eu and temperature activated energy transfer from terbium to europium |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2021 |b ScienceDirect |
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| 520 | _ | _ | |a K$_5$GdLi$_2$F$_{10}$ compound doped with Tb$^{3+}$ and Eu$^{3+}$ was synthetized. The excited states of these lanthanide ions were analyzed up to VUV range at 125,000 cm$^{−1}$ (80 nm). Strong coupling between terbium and europium was found. The energy transfer processes from terbium to europium mainly depend on fast migration. The lifetime of $^5$D$_4$ multiplet in the presence of europium is shorter by about 30% in comparison to singly doped terbium compounds. The character of the decay curve of the $^5$D$_4$ multiplet is mono-exponential. Non-exponential character was discovered in the case of $^5$D$_1$ europium multiplet in the presence of terbium. The nature of this quenching was determined to be dipole-dipole interaction with critical distance 9.96 Å. The energy transfer is temperature dependent. |
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| 773 | _ | _ | |a 10.1016/j.jallcom.2020.157459 |g Vol. 855, p. 157459 - |0 PERI:(DE-600)2012675-X |p 157459 |t Journal of alloys and compounds |v 855 |y 2021 |x 0925-8388 |
| 856 | 4 | _ | |u https://www.sciencedirect.com/science/article/abs/pii/S0925838820338238 |
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