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000449133 245__ $$aEffect of silver nanoparticle doping on the physicochemical properties of a room temperature ferroelectric liquid crystal mixture
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000449133 520__ $$aWe have investigated the effect of doping of a small amount of silver nanoparticles (AgNPs) on the physicochemical properties of a room temperature ferroelectric liquid crystal mixture. Polarizing optical microscopy, differential scanning calorimetry, synchrotron X-ray diffraction, dielectric and electro-optic studies showed that the inclusion of AgNPs greatly influences the phase transition temperatures, structural, dielectric, and electro-optic properties. Doping slightly decreases the SmC*-SmA* and SmA*-Iso transition temperatures signifying decreased ordering which is also reflected in reduced tilt angles. The Goldstone mode dielectric increment of the nanocomposite increases twofold but the critical frequency decreases slightly. Spontaneous polarization of the mixture also increases significantly in the presence of AgNPs whereas the conductivity decreases indicating trapping of ions by the nanoparticles. Goldstone mode rotational viscosity decreases and as a result of which the switching time also decreases by 88 μs making the nano doped mixture more suitable for practical applications.
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000449133 7001_ $$0P:(DE-H253)PIP1015208$$aMandal, Pradip Kumar$$b1$$eCorresponding author
000449133 7001_ $$0P:(DE-H253)PIP1014217$$aSarma, Abhisakh$$b2$$udesy
000449133 7001_ $$0P:(DE-H253)PIP1007064$$aGutowski, Olof$$b3$$udesy
000449133 773__ $$0PERI:(DE-600)1491496-7$$a10.1016/j.molliq.2020.114185$$gVol. 319, p. 114185 -$$p114185$$tJournal of molecular liquids$$v319$$x0167-7322$$y2020
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