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@ARTICLE{Wagstaffe:441139,
author = {Wagstaffe, Michael and Noei, Heshmat and Stierle, Andreas},
title = {{E}lucidating the {D}efect-{I}nduced {C}hanges in the
{P}hotocatalytic {A}ctivity of ${T}i{O}_{2}$},
journal = {The journal of physical chemistry / C},
volume = {124},
number = {23},
issn = {1932-7455},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PUBDB-2020-02336},
pages = {12539 - 12547},
year = {2020},
note = {Waiting for fulltext},
abstract = {The adsorption and subsequent photo-oxidation ofcarbon
monoxide on the anatase TiO2(101) and rutile TiO2(110)single
crystal surfaces was investigated using low temperature
X-rayphotoelectron spectroscopy. Anatase was shown to
significantlyoutperform rutile in terms of the rate of
carbon dioxide yield onthe stoichiometric surface, and
further to this, the presence ofdefects was shown to heavily
influence the photocatalyticefficiency. The oxidation rate
was reduced on anatase but increasedon rutile. This change
is attributed to the location of defects withinthe crystal
structure and is further discussed in this work.
Thesefindings are of significant importance and demonstrate
the possibilities of defect engineering in photocatalysis.},
cin = {FS-NL},
ddc = {530},
cid = {I:(DE-H253)FS-NL-20120731},
pnm = {6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G2 - FLASH (POF3-622) / SFB 986
A07 - Adsorption organischer Säuren auf Oxidoberflächen
und Nanostrukturen (A07) (318017425) / AIM - CUI: Advanced
Imaging of Matter (390715994)},
pid = {G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G2 /
G:(GEPRIS)318017425 / G:(GEPRIS)390715994},
experiment = {EXP:(DE-H253)F-PG2-20150101 /
EXP:(DE-H253)Nanolab-02-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000541745800040},
doi = {10.1021/acs.jpcc.0c02809},
url = {https://bib-pubdb1.desy.de/record/441139},
}