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@ARTICLE{ArdilaFierro:439032,
author = {Ardila-Fierro, Karen J. and Lukin, Stipe and Etter, Martin
and Užarević, Krunoslav and Halasz, Ivan and Bolm, Carsten
and Hernandez, Jose},
title = {{D}irect {V}isualization of a {M}echanochemically {I}nduced
{M}olecular {R}earrangement},
journal = {Angewandte Chemie / International edition International
edition},
volume = {59},
number = {32},
issn = {1433-7851},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {PUBDB-2020-02175},
pages = {13458-13462},
year = {2020},
abstract = {Recent progress in the field of mechanochemistry has
expanded the discovery of mechanically induced chemical
transformations to several areas of science. However, a
general fundamental understanding of how mechanochemical
reactions by ball milling occur has remained unreached. For
this, we have now implemented in situ monitoring of a
mechanochemically induced molecular rearrangement by
synchrotron X‐ray powder diffraction, Raman spectroscopy,
and real‐time temperature sensing. The results of this
study demonstrate that molecular rearrangements can be
accomplished in the solid state by ball milling and how
in situ monitoring techniques enable the visualization of
changes occurring at the exact instant of a molecular
migration. The mechanochemical benzil–benzilic acid
rearrangement is the focal point of the study.},
cin = {DOOR ; HAS-User / FS-PET-D},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PET-D-20190712},
pnm = {6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G3 - PETRA III (POF3-622)},
pid = {G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G3},
experiment = {EXP:(DE-H253)P-P02.1-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:32187814},
UT = {WOS:000539448300001},
doi = {10.1002/anie.201914921},
url = {https://bib-pubdb1.desy.de/record/439032},
}