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| Home > Publications database > Stoichiometric deviations in bond distances in the mixed $As_{2}S_{3}-As_{2}Se_{3}$ system: Raman spectroscopy and EXAFS studies > print |
| Home > Publications database > Stoichiometric deviations in bond distances in the mixed $As_{2}S_{3}-As_{2}Se_{3}$ system: Raman spectroscopy and EXAFS studies > print |
| 001 | 429371 | ||
| 005 | 20250729163206.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jnoncrysol.2019.119533 |2 doi |
| 024 | 7 | _ | |a 0022-3093 |2 ISSN |
| 024 | 7 | _ | |a 1873-4812 |2 ISSN |
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| 100 | 1 | _ | |a Stronski, A. |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Stoichiometric deviations in bond distances in the mixed $As_{2}S_{3}-As_{2}Se_{3}$ system: Raman spectroscopy and EXAFS studies |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2019 |b Elsevier Science |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 500 | _ | _ | |a © Elsevier B.V.; Full published version in progress; Post referee fulltext in progress; Embargo 12 months from publication |
| 520 | _ | _ | |a Raman spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy have been applied to find evidence for isostructural substitution of chalcogen atoms in pyramidal structural units of network glasses from stoichiometric/pseudo-binary As2S3-As2Se3 system. The obtained values of the nearest neighbours atomic distance (rAs-Se = 2.37 ± 0.01 Å; rAs-S = 2.33 ± 0.01 Å for As40Se30S30) suggest the existence of mixed AsS2Se and AsSe2S pyramids in which each of As atoms is bonded with S and/or Se atoms in relation to S/Se ratio in composition, while Se atoms are bonded only with As ones with the same bond distance in the form of = As-Se-As = bridges that connect the main pyramidal structural units. No evidence for existence of heteroatomic or heteronuclear SeS bonding is found for the examined glasses |
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| 700 | 1 | _ | |a Revutska, L. |0 P:(DE-HGF)0 |b 2 |
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| 773 | _ | _ | |a 10.1016/j.jnoncrysol.2019.119533 |g Vol. 521, p. 119533 - |0 PERI:(DE-600)1500501-x |p 119533 (6 pages) |t Journal of non-crystalline solids |v 521 |y 2019 |x 0022-3093 |
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