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000426632 1001_ $$0P:(DE-H253)PIP1031546$$aYachmenev, Andrey$$b0$$eCorresponding author
000426632 245__ $$aField-induced diastereomers for chiral separation
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000426632 520__ $$aA novel approach for the state-specific enantiomeric enrichment and the spatial separation ofenantiomers is presented. Our scheme utilizes techniques from strong-field laser physics, specificallyan optical centrifuge in conjunction with a static electric field, to create a chiral field with definedhandedness. Molecular enantiomers experience unique rotational excitation dynamics and thiscan be exploited to spatially separate the enantiomers using electrostatic deflection. Notably, therotational-state-specific enantiomeric enhancement and its handedness is fully controllable. Toexplain these effects, the conceptual framework of field-induced diastereomers of a chiral molecule isintroduced and computationally demonstrated through robust quantum-mechanical simulations onthe prototypical chiral molecule propylene oxide (C$_3$H$_6$O), for which ensembles with an enantiomericexcess of up to 30 % were obtained.
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000426632 7870_ $$0PUBDB-2024-05026$$aYachmenev, Andrey et.al.$$d2019$$iIsParent$$rarXiv:1905.07166$$tField-Induced Diastereomers for Chiral Separation
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