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@ARTICLE{Kavi:426525,
      author       = {Kavčič, Anja and Mikuš, Klemen and Debeljak, Marta and
                      Teun van Elteren, Johannes and Arčon, Iztok and Kodre,
                      Alojz and Kump, Peter and Karydas, Andreas Germanos and
                      Migliori, Alessandro and Czyzycki, Mateusz and Vogel-Mikuš,
                      Katarina},
      title        = {{L}ocalization, ligand environment, bioavailability and
                      toxicity of mercury in {B}oletus spp. and {S}cutiger
                      pes-caprae mushrooms},
      journal      = {Ecotoxicology and environmental safety},
      volume       = {184},
      issn         = {0147-6513},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2019-03780},
      pages        = {109623 -},
      year         = {2019},
      note         = {© The Authors. Published by Elsevier Inc.},
      abstract     = {This study provides information on mercury (Hg)
                      localization, speciation and ligand environment in edible
                      mushrooms: Boletus edulis, B. aereus and Scutiger pes-caprae
                      collected at non-polluted and Hg polluted sites, by
                      LA-ICP-MS, SR-μ-XRF and Hg L3-edge XANES and EXAFS.
                      Mushrooms (especially young ones) collected at Hg polluted
                      sites can contain more than 100 μg Hg g−1 of dry mass.
                      Imaging of the element distribution shows that Hg
                      accumulates mainly in the spore-forming part (hymenium) of
                      the cap. Removal of hymenium before consumption can
                      eliminate more than $50\%$ of accumulated Hg.Mercury is
                      mainly coordinated to di-thiols $(43–82\%),$ followed by
                      di-selenols $(13–35\%)$ and tetra-thiols $(12–20\%).$
                      Mercury bioavailability, as determined by feeding the
                      mushrooms to Spanish slugs (known metal bioindicators owing
                      to accumulation of metals in their digestive gland), ranged
                      from $4\%$ (S. pes-caprae) to $30\%$ (B. aereus), and
                      decreased with increasing selenium (Se) levels in the
                      mushrooms. Elevated Hg levels in mushrooms fed to the slugs
                      induced toxic effects, but these effects were counteracted
                      with increasing Se concentrations in the mushrooms, pointing
                      to a protective role of Se against Hg toxicity through HgSe
                      complexation. Nevertheless, consumption of the studied
                      mushroom species from Hg polluted sites should be avoided.},
      cin          = {DOOR},
      ddc          = {610},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (POF3-622) / FS-Proposal: I-20160764 EC
                      (I-20160764-EC) / CALIPSOplus - Convenient Access to Light
                      Sources Open to Innovation, Science and to the World
                      (730872)},
      pid          = {G:(DE-HGF)POF3-6G3 / G:(DE-H253)I-20160764-EC /
                      G:(EU-Grant)730872},
      experiment   = {EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:31518823},
      UT           = {WOS:000489085200013},
      doi          = {10.1016/j.ecoenv.2019.109623},
      url          = {https://bib-pubdb1.desy.de/record/426525},
}