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@ARTICLE{Sarma:426213,
      author       = {Sarma, Abhisakh and Dippel, Ann-Christin and Gutowski, Olof
                      and Etter, Martin and Lippmann, Milena and Seeck, Oliver and
                      Manna, Gouranga and Sanyal, Milan and Keller, Thomas F. and
                      Kulkarni, Satishkumar and Guha, Puspendu and Satyam,
                      Parlapali V. and von Zimmermann, Martin},
      title        = {{E}lectrodeposition of nanowires of a high copper content
                      thiourea precursor of copper sulfide},
      journal      = {RSC Advances},
      volume       = {9},
      number       = {55},
      issn         = {2046-2069},
      address      = {London},
      publisher    = {RSC Publishing},
      reportid     = {PUBDB-2019-03632},
      pages        = {31900 - 31910},
      year         = {2019},
      abstract     = {Copper thiourea complexes are an important material class
                      for application as a precursor of copper sulfidenanocrystals
                      with potential use in solar cells, optoelectronics,
                      medicine, etc. They represent a type of singlesource
                      precursor, comprising both copper and sulfur in one chemical
                      compound, whose tunablestoichiometry and morphology enable
                      control of the quality and properties of the synthesized
                      coppersulfide nanocrystals. Here, we present a template free
                      electrochemical route to prepare nanowires ofcopper thiourea
                      (tu) chloride hemihydrate ([Cu(tu)]Cl.1/2H2O) by pulse
                      deposition. We proposed the modelof the growth of nanowires.
                      We also demonstrate complete transformation from the
                      precursor tocopper sulfide nanowire by heating it to 180 C
                      that involves $20\%$ volume loss due to the decompositionof
                      organic constituents; the obtained nanowires have around
                      $38\%$ covellite (CuS) and $62\%$ digenite(Cu1.8S) phases.
                      Electrochemistry offers the advantage of spatially selected
                      deposition e.g. in the activeregions of a device.},
      cin          = {FS-PET-D / FS-NL / DOOR ; HAS-User / FS-TI},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-PET-D-20190712 / I:(DE-H253)FS-NL-20120731 /
                      I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-TI-20120731},
      pnm          = {6G3 - PETRA III (POF3-622) / 6213 - Materials and Processes
                      for Energy and Transport Technologies (POF3-621) /
                      INDIA-DESY - INDIA-DESY Collaboration
                      $(2020_Join2-INDIA-DESY)$},
      pid          = {G:(DE-HGF)POF3-6G3 / G:(DE-HGF)POF3-6213 /
                      $G:(DE-HGF)2020_Join2-INDIA-DESY$},
      experiment   = {EXP:(DE-H253)P-P07-20150101 /
                      EXP:(DE-H253)Nanolab-04-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000490133300012},
      doi          = {10.1039/C9RA04293H},
      url          = {https://bib-pubdb1.desy.de/record/426213},
}