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@ARTICLE{Rohlf:424560,
      author       = {Rohlf, Sebastian and Grunwald, Jan and Jasper-Toennies,
                      Torben and Johannsen, Sven and Diekmann, Florian and
                      Studniarek, Michał and Berndt, Richard and Tuczek, Felix
                      and Rossnagel, Kai and Gruber, Manuel},
      title        = {{I}nfluence of {S}ubstrate {E}lectronic {P}roperties on the
                      {I}ntegrity and {F}unctionality of an {A}dsorbed {F}e({II})
                      {S}pin-{C}rossover {C}ompound},
      journal      = {The journal of physical chemistry / C},
      volume       = {123},
      number       = {29},
      issn         = {1932-7447},
      address      = {Washington, DC},
      publisher    = {ACS},
      reportid     = {PUBDB-2019-02991},
      pages        = {17774 - 17780},
      year         = {2019},
      note         = {© American Chemical Society},
      abstract     = {The bistability of spin-crossover complexes on surfaces is
                      of great interest for potential applications. Using X-ray
                      absorption spectroscopy, we investigated the properties of
                      [Fe(pypyr(CF$_3$)$_2$)$_2$(phen)] (pypyr =
                      2-(2′-pyridyl)pyrrolide, phen = 1,10-phenanthroline), a
                      vacuum-evaporable Fe(II) complex, in direct contact to a set
                      of substrates. The electronic properties of these substrates
                      range from metallic to semiconducting. While dissociation is
                      observed on metal surfaces, efficient light-induced
                      switching is realized on semimetallic and semiconducting
                      surfaces. This indicates that the density of states of the
                      substrate at the Fermi level plays a role for the integrity
                      and functionality of the adsorbed compound. In an
                      intermediate case, namely, [Fe(pypyr(CF$_3$)$_2$)$_2$(phen)]
                      on graphene/Ni(111), functional and dissociated species are
                      found to coexist. This result indicates that some previous
                      studies may deserve to be reconsidered because the
                      possibility of coexisting intact and fragmented
                      spin-crossover complexes was neglected.},
      cin          = {FS-SXQM / UKiel},
      ddc          = {530},
      cid          = {I:(DE-H253)FS-SXQM-20190201 / I:(DE-H253)UKiel-20120814},
      pnm          = {6212 - Quantum Condensed Matter: Magnetism,
                      Superconductivity (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6212},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000477785000016},
      doi          = {10.1021/acs.jpcc.9b02845},
      url          = {https://bib-pubdb1.desy.de/record/424560},
}