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@ARTICLE{Wenig:423815,
author = {Wenig, K. and Wieland, Marek and Baumann, Arne and Walther,
S. and Dimitriou, Anastasios and Prandolini, M. J. and
Schepp, Oliver and Bermúdez Macias, I. and Sumfleth, Malte
and Stojanovic, N. and Düsterer, S. and
Rönsch-Schulenburg, Juliane and Zapolnova, E. and Pan, R.
and Drescher, M. and Fruehling, Ulrike},
title = {{E}lectronic decay of core-excited {HC}l molecules probed
by {TH}z streaking},
journal = {Structural dynamics},
volume = {6},
number = {3},
issn = {2329-7778},
address = {Melville, NY},
publisher = {AIP Publishing LLC},
reportid = {PUBDB-2019-02676},
pages = {034301},
year = {2019},
abstract = {The ultrafast electronic decay of HCl molecules in the time
domain after resonant core excitation was measured. Here, a
Cl-2p core electron was promoted to the antibonding σ*
orbital initiating molecular dissociation, and
simultaneously, the electronic excitation relaxes via an
Auger decay. For HCl, both processes compete on similar
ultrashort femtosecond time scales. In order to measure the
lifetime of the core hole excitation, we collinearly
superimposed 40 fs soft x-ray pulses with intense terahertz
(THz) radiation from the free-electron laser in Hamburg
(FLASH). Electrons emitted from the molecules are
accelerated (streaked) by the THz electric field where the
resulting momentum change depends on the field's phase at
the instant of ionization. Evaluation of a time-shift
between the delay-dependent streaking spectra of photo- and
Auger electrons yields a decay constant of (11 ± 2) fs
for LMM Auger electrons. For further validation, the method
was also applied to the MNN Auger decay of krypton.
Reproduction of the value already published in the
literature confirms that a temporal resolution much below
the duration of the exciting x-ray pulses can be reached.},
cin = {FS-FLASH-B / FS-FLASH-D / MFL / U HH / CFEL-FXP},
ddc = {500},
cid = {I:(DE-H253)FS-FLASH-B-20160930 /
I:(DE-H253)FS-FLASH-D-20160930 / I:(DE-H253)MFL-20120731 /
$I:(DE-H253)U_HH-20120814$ / I:(DE-H253)CFEL-FXP-20160909},
pnm = {6211 - Extreme States of Matter: From Cold Ions to Hot
Plasmas (POF3-621) / DFG project 194651731 - EXC 1074:
Hamburger Zentrum für ultraschnelle Beobachtung (CUI):
Struktur, Dynamik und Kontrolle von Materie auf atomarer
Skala (194651731) / DFG project 390715994 - EXC 2056: CUI:
Advanced Imaging of Matter (390715994)},
pid = {G:(DE-HGF)POF3-6211 / G:(GEPRIS)194651731 /
G:(GEPRIS)390715994},
experiment = {EXP:(DE-H253)F-BL3-20150101 /
EXP:(DE-H253)F-ThzBL-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:31123698},
UT = {WOS:000474442500002},
doi = {10.1063/1.5091756},
url = {https://bib-pubdb1.desy.de/record/423815},
}