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100 1 _ |0 P:(DE-HGF)0
|a Miliani, Costanza
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245 _ _ |a Photochemistry of Artists’ Dyes and Pigments: Towards Better Understanding and Prevention of Colour Change in Works of Art
260 _ _ |a Weinheim
|b Wiley-VCH
|c 2018
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500 _ _ |a (c) Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim ; Post referee fulltext in progress 2; Embargo 12 months from publication
520 _ _ |a The absorptionof lightgivesapigmentits colourand its reasonforbeing,but it alsocreatesexcitedstates,that is,new moleculeswithanenergyexcessthat can be dissipatedthroughdegradationpathways.Photodegradationprocessesprovokelong-term,cumulativeand irre-versiblecolourchanges(fading,darkening,blanching) of whichthepredictionand preventionare challengingtasks.Ofall the environ-mentalrisksthat affectheritagematerials,light exposureis the onlyone that cannotbe controlledwithoutany impacton the optimaldis-playof the exhibit.Light-inducedalterationsare not onlyassociatedwiththe pigmentitselfbut also withits interactionswithsupport/binderand,in turn,are furthercomplicatedby the natureof the environ-mentalconditions.Inthis Minireviewwe investigatehowchemistry,encompassingmulti-scaleanalyticalinvestigationsof worksof art,computationalmodellingand physicaland chemicalstudiescontrib-utes to improveour predictionof artworkappearancebeforedegra-dationand to establisheffectivepreventiveconservationstrategies.
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|g Vol. 57, no. 25, p. 7324 - 7334
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|t Angewandte Chemie / International edition International edition
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