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000421264 1001_ $$0P:(DE-H253)PIP1005590$$aLippmann, Milena$$b0$$eCorresponding author
000421264 245__ $$aExperimental Observation of Crystal–Liquid Coexistence in Slit-Confined Nonpolar Fluids
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000421264 520__ $$aFilms of carbon tetrachloride (CCl$_4$) confined in slit geometry between two flat diamond substrates down to a few tens of Angstroms are studied by combining X-ray reflectivity with in-plane and out-of-plane X-ray scattering. The confined films form a heterogeneous structure with coexisting regions of liquid and crystalline phases. The liquid phase shows short-range ordering normal to the surfaces of the substrates. The experiments directly show the ability of the confinement to induce crystal objects, which is a long-discussed issue in the literature. The surface structure and morphology of the substrates may influence the actual realization of the crystalline phase in confinement.
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000421264 773__ $$0PERI:(DE-600)2522838-9$$a10.1021/acs.jpclett.9b00331$$gVol. 10, no. 7, p. 1634 - 1638$$n7$$p1634 - 1638$$tThe journal of physical chemistry letters$$v10$$x1948-7185$$y2019
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