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@ARTICLE{Hamed:421193,
author = {Hamed, Mai Hussein and Hinz, Ronja Anika and Lömker,
Patrick and Wilhelm, Marek and Gloskovskii, Andrei and
Bencok, Peter and Schmitz-Antoniak, Carolin and Elnaggar,
Hebatalla and Schneider, Claus M. and Mueller, Martina},
title = {{T}unable {M}agnetic {P}hases at
$\mathrm{{F}e_{3}{O}_{4}/{S}r{T}i{O}_{3}}$ {O}xide
{I}nterfaces},
journal = {ACS applied materials $\&$ interfaces},
volume = {11},
number = {7},
issn = {1944-8252},
address = {Washington, DC},
publisher = {ACS},
reportid = {PUBDB-2019-01899},
pages = {7576 - 7583},
year = {2019},
note = {© American Chemical Society; Post referee fulltext in
progress 2; Embargo 12 months from publication},
abstract = {We demonstrate the emergence and control of magnetic phases
between magnetite (Fe$_3$O$_4$), a ferrimagnetic halfmetal,
and SrTiO$_3$, a transparent nonmagnetic insulator
considered the bedrock of oxide-based electronics. The
Verwey transition (T$_V$) was detected to persist from
bulk-like down to ultrathin Fe$_3$O$_4$ films, decreasing
from 117 ± 4 K (38 nm) to 25 ± 4 K (2 nm), respectively.
Element-selective electronic and magnetic properties of the
ultrathin films and buried interfaces are studied by
angle-dependent hard X-ray photoelectron spectroscopy and
X-ray magnetic circular dichroism techniques. We observe a
reduction of Fe$^{2+}$ ions with decreasing film thickness,
accompanied by an increase of Fe$^{3+}$ ions in both
tetrahedral and octahedral sites and conclude on the
formation of a magnetically active ferrimagnetic 2 u.c.
γ-Fe$_2$O$_3$ intralayer. To manipulate the interfacial
magnetic phase, a postannealing process causes the
controlled reduction of the γ-Fe$_2$O$_3$ that finally
leads to stoichiometric and ferrimagnetic
Fe$_3$O$_4$/SrTiO$_3$(001) heterointerfaces.},
cin = {DOOR / FS-PEX},
ddc = {600},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PEX-20130206},
pnm = {6212 - Quantum Condensed Matter: Magnetism,
Superconductivity (POF3-621) / 6G3 - PETRA III (POF3-622)},
pid = {G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6G3},
experiment = {EXP:(DE-H253)P-P09-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30672270},
UT = {WOS:000459642200097},
doi = {10.1021/acsami.8b20625},
url = {https://bib-pubdb1.desy.de/record/421193},
}