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@ARTICLE{Timoshenko:421185,
author = {Timoshenko, Janis and Anspoks, Andris and Kalinko, Alexandr
and Kuzmin, Alexei},
title = {{T}hermal disorder and correlation effects in
anti-perovskite-type copper nitride},
journal = {Acta materialia},
volume = {129},
issn = {1359-6454},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PUBDB-2019-01894},
pages = {61 - 71},
year = {2017},
note = {© Acta Materialia Inc},
abstract = {Reverse Monte Carlo simulations coupled with evolutionary
algorithm were employed for the analysis of the temperature
dependent (10–300 K) Cu K-edge extended X-ray absorption
fine structure (EXAFS) spectra of polycrystalline copper
nitride (Cu$_3$N) with the goal to extract information on
the thermal disorder and interatomic correlations in
anti-perovskite-type crystal lattice. The obtained results
are discussed in comparison with metallic copper and
perovskite-type rhenium trioxide. The analysis of EXAFS
spectra suggests that the anisotropy of copper atom
vibrations is significantly enhanced upon increasing
temperature, leading to pronounced tilting motion of NCu$_6$
octahedra. Strong correlation in the motion of atoms was
found along –N–Cu–N– atomic chains but it reduces
rapidly with an increase of interatomic distance. Finally,
anticorrelated motion of neighboring Cu atoms occurs along
Cu–Cu bonds and is consistent with breathing-type motion
of NCu$_6$ octahedra.},
cin = {DOOR},
ddc = {670},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
experiment = {EXP:(DE-H253)D-C-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000400033900007},
doi = {10.1016/j.actamat.2017.02.074},
url = {https://bib-pubdb1.desy.de/record/421185},
}