guest ::
| Home > Publications database > General Synthesis of Ordered Mesoporous Rare-Earth Orthovanadate Thin Films and Their Use as Photocatalysts and Phosphors for Lighting Applications > print |
| Home > Publications database > General Synthesis of Ordered Mesoporous Rare-Earth Orthovanadate Thin Films and Their Use as Photocatalysts and Phosphors for Lighting Applications > print |
| 001 | 420142 | ||
| 005 | 20250729162436.0 | ||
| 024 | 7 | _ | |a 10.1021/acsanm.8b02327 |2 doi |
| 024 | 7 | _ | |a altmetric:55315711 |2 altmetric |
| 024 | 7 | _ | |a 10.3204/PUBDB-2019-01329 |2 datacite_doi |
| 024 | 7 | _ | |a WOS:000469409900049 |2 WOS |
| 024 | 7 | _ | |a openalex:W2911936543 |2 openalex |
| 037 | _ | _ | |a PUBDB-2019-01329 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Reitz, Christian |0 P:(DE-H253)PIP1011585 |b 0 |e Corresponding author |
| 245 | _ | _ | |a General Synthesis of Ordered Mesoporous Rare-Earth Orthovanadate Thin Films and Their Use as Photocatalysts and Phosphors for Lighting Applications |
| 260 | _ | _ | |a Washington, DC |c 2019 |b ACS Publications |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1552324382_14795 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 500 | _ | _ | |a © American Chemical Society |
| 520 | _ | _ | |a The block copolymer templating sol–gel synthesis of a novel class of ternary oxide nanomaterials is reported. NdVO$_4$, EuVO$_4$, GdVO$_4$, DyVO$_4$, YVO$_4$, and TmVO$_4$ have been prepared as open mesoporous films by the dip-coating method using hydrated rare-earth nitrate salt precursors along with vanadium oxytrichloride. All materials crystallize in the tetragonal ZrSiO$_4$-type structure with space group I4$_1$/amd. Short-term treatment at 550 °C is found sufficient to initiate crystallization. Characterization via X-ray and electron diffraction, Raman and X-ray photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry confirms the single-phase nature and uniformity of the different orthovanadates with tailorable crystallite sizes. The integrated results from electron and atomic force microscopy, Kr physisorption, and in situ and ex situ synchrotron-based small-angle X-ray scattering reveal that the porosity persists throughout the thickness of films, and the mesoscopic ordering is retained even after heating in air at 700 °C. Photobleaching experiments indicate that the sol–gel derived materials, showing an indirect band gap transition at 3.8 ± 0.1 eV, exhibit good photocatalytic properties—the activity is highly superior to that of bulk films of the same nominal composition. Moreover, when doping GdVO$_4$, YVO$_4$, and solid solution GdVO$_4$–YVO$_4$ with trivalent rare-earth ions such as Eu$^{3+}$, Dy$^{3+}$, Er$^{3+}$, or Tm$^{3+}$ ions, the films hold promise as phosphors for lighting applications, which might pave the way toward development of (3-dimensional) intricate nanocomposites with unprecedented functionalities. |
| 536 | _ | _ | |a 899 - ohne Topic (POF3-899) |0 G:(DE-HGF)POF3-899 |c POF3-899 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 693 | _ | _ | |a DORIS III |f DORIS Beamline BW4 |1 EXP:(DE-H253)DORISIII-20150101 |0 EXP:(DE-H253)D-BW4-20150101 |6 EXP:(DE-H253)D-BW4-20150101 |x 0 |
| 700 | 1 | _ | |a Smarsly, Bernd |0 P:(DE-H253)PIP1012200 |b 1 |
| 700 | 1 | _ | |a Brezesinski, Torsten |0 P:(DE-HGF)0 |b 2 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acsanm.8b02327 |g Vol. 2, no. 2, p. 1063 - 1071 |0 PERI:(DE-600)2916552-0 |n 2 |p 1063 - 1071 |t ACS applied nano materials |v 2 |y 2019 |x 2574-0970 |
| 856 | 4 | _ | |u https://pubs.acs.org/doi/10.1021/acsanm.8b02327 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.pdf |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.pdf |y Restricted |z StatID:(DE-HGF)0599 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.gif?subformat=icon |x icon |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.jpg?subformat=icon-1440 |x icon-1440 |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.jpg?subformat=icon-180 |x icon-180 |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.jpg?subformat=icon-640 |x icon-640 |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/MS_post-referee.pdf?subformat=pdfa |x pdfa |y Published on 2019-01-28. Available in OpenAccess from 2020-01-28. |z StatID:(DE-HGF)0510 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.gif?subformat=icon |x icon |y Restricted |z StatID:(DE-HGF)0599 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |z StatID:(DE-HGF)0599 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.jpg?subformat=icon-180 |x icon-180 |y Restricted |z StatID:(DE-HGF)0599 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.jpg?subformat=icon-640 |x icon-640 |y Restricted |z StatID:(DE-HGF)0599 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/420142/files/acsanm.8b02327.pdf?subformat=pdfa |x pdfa |y Restricted |z StatID:(DE-HGF)0599 |
| 909 | C | O | |o oai:bib-pubdb1.desy.de:420142 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 0 |6 P:(DE-H253)PIP1011585 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 1 |6 P:(DE-H253)PIP1012200 |
| 913 | 1 | _ | |a DE-HGF |b Programmungebundene Forschung |l ohne Programm |1 G:(DE-HGF)POF3-890 |0 G:(DE-HGF)POF3-899 |2 G:(DE-HGF)POF3-800 |v ohne Topic |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |
| 914 | 1 | _ | |y 2019 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a No Authors Fulltext |0 StatID:(DE-HGF)0550 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-H253)HAS-User-20120731 |k DOOR |l DOOR-User |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-H253)HAS-User-20120731 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|