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| 001 | 419010 | ||
| 005 | 20211110153527.0 | ||
| 024 | 7 | _ | |a 10.1103/PhysRevLett.120.133203 |2 doi |
| 024 | 7 | _ | |a 0031-9007 |2 ISSN |
| 024 | 7 | _ | |a 1079-7114 |2 ISSN |
| 024 | 7 | _ | |a 1092-0145 |2 ISSN |
| 024 | 7 | _ | |a 10.3204/PUBDB-2019-00874 |2 datacite_doi |
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| 100 | 1 | _ | |a Kroll, Thomas |0 P:(DE-H253)PIP1010158 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Stimulated X-Ray Emission Spectroscopy in Transition Metal Complexes |
| 260 | _ | _ | |a College Park, Md. |c 2018 |b APS |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a We report the observation and analysis of the gain curve of amplified $Kα$ x-ray emission from solutions of Mn(II) and Mn(VII) complexes using an x-ray free electron laser to create the $1s$ core-hole population inversion. We find spectra at amplification levels extending over 4 orders of magnitude until saturation. We observe bandwidths below the Mn 1s core-hole lifetime broadening in the onset of the stimulated emission. In the exponential amplification regime the resolution corrected spectral width of ∼1.7 eV FWHM is constant over 3 orders of magnitude, pointing to the buildup of transform limited pulses of ∼1 fs duration. Driving the amplification into saturation leads to broadening and a shift of the line. Importantly, the chemical sensitivity of the stimulated x-ray emission to the Mn oxidation state is preserved at power densities of $∼10^{20}$ $W/cm^2$ for the incoming x-ray pulses. Differences in signal sensitivity and spectral information compared to conventional (spontaneous) x-ray emission spectroscopy are discussed. Our findings build a baseline for nonlinear x-ray spectroscopy for a wide range of transition metal complexes in inorganic chemistry, catalysis, and materials science. |
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| 700 | 1 | _ | |a Weninger, Clemens |b 1 |
| 700 | 1 | _ | |a Alonso-Mori, Roberto |b 2 |
| 700 | 1 | _ | |a Sokaras, Dimosthenis |b 3 |
| 700 | 1 | _ | |a Zhu, Diling |b 4 |
| 700 | 1 | _ | |a Mercadier, Laurent |b 5 |
| 700 | 1 | _ | |a Majety, Vinay P. |0 P:(DE-H253)PIP1032833 |b 6 |
| 700 | 1 | _ | |a Marinelli, Agostino |b 7 |
| 700 | 1 | _ | |a Lutman, Alberto |b 8 |
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| 700 | 1 | _ | |a Boutet, Sébastien |b 11 |
| 700 | 1 | _ | |a Aquila, Andy |b 12 |
| 700 | 1 | _ | |a Koglin, Jason |b 13 |
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| 700 | 1 | _ | |a Kern, Jan |b 16 |
| 700 | 1 | _ | |a Fuller, Franklin D. |b 17 |
| 700 | 1 | _ | |a Pastor, Ernest |b 18 |
| 700 | 1 | _ | |a Fransson, Thomas |b 19 |
| 700 | 1 | _ | |a Zhang, Yu |b 20 |
| 700 | 1 | _ | |a Yano, Junko |b 21 |
| 700 | 1 | _ | |a Yachandra, Vittal K. |b 22 |
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| 700 | 1 | _ | |a Bergmann, Uwe |b 24 |
| 773 | _ | _ | |a 10.1103/PhysRevLett.120.133203 |g Vol. 120, no. 13, p. 133203 |0 PERI:(DE-600)1472655-5 |n 13 |p 133203 |t Physical review letters |v 120 |y 2018 |x 1079-7114 |
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