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@PHDTHESIS{Laurus:418948,
author = {Laurus, Torsten},
othercontributors = {Weckert, Edgar and Wurth, Wilfried},
title = {{D}iffraction anomalous fine structure in {L}aue geometry},
school = {Universität Hamburg},
type = {Dissertation},
address = {Hamburg},
publisher = {Verlag Deutsches Elektronen-Synchrotron},
reportid = {PUBDB-2019-00851, DESY-THESIS-2018-043},
series = {DESY-THESIS},
pages = {108},
year = {2016},
note = {Dissertation, Universität Hamburg, 2016},
abstract = {This thesis deals with the further development of the
method of Borrmannspectroscopy and the development of the
novel method of diffractionanomalous fine structure in Laue
geometry.Borrmann spectroscopy utilizes the Borrmann effect
in order to enhancethe quadrupol absorption, which enables
studying weak quadrupoltransitions. In the present work a
model is developed, which describes thedependence of the
quadrupol enhancement on temperature and anisotropyof the
chemical environment. This model is used to describe the
Borrmannspectroscopy results obtained from a strontium
titanate single crystal.Furthermore, the influence of the
mosaicity of real crystals on thequadrupole enhancement is
studied by means of simulations, which arebased on the
dynamical theory of diffraction and a modified
structuremodel of barium titanate.The method of diffraction
anomalous fine structure (DAFS) is based onthe combination
of X-ray diffraction and absorption spectroscopy and
allowsinvestigating the local atomic structure of
centrosymmetric crystalsutilising the additional selectivity
due to diffraction. In the present workthe novel method of
diffraction anomalous fine struture in Laue geometry(LDAFS)
is developed. It utilizes the intensity of the Laue
geometrydiffracted beam, which experiences an altered
absorption due to the Borrmanneffect. Its experimental
applicability is verified by experiments ona barium titanate
single crystal and comparison with conventional
X-rayabsorption spectroscopy results.},
cin = {FS-PS},
cid = {I:(DE-H253)FS-PS-20131107},
pnm = {632 - Detector technology and systems (POF3-632)},
pid = {G:(DE-HGF)POF3-632},
experiment = {EXP:(DE-H253)D-W1-20150101 / EXP:(DE-H253)D-A1-20150101},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)29 / PUB:(DE-HGF)11},
doi = {10.3204/PUBDB-2019-00851},
url = {https://bib-pubdb1.desy.de/record/418948},
}