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@ARTICLE{AndroDubraja:418800,
author = {Androš Dubraja, Lidija and Kruk, Robert and Brezesinski,
Torsten},
title = {{R}obust {M}acroscopic {P}olarization of {B}lock
{C}opolymer-{T}emplated {M}esoporous {P}erovskite-{T}ype
{T}hin-{F}ilm {F}erroelectrics},
journal = {Advanced electronic materials},
volume = {5},
number = {1},
issn = {2199-160X},
address = {Chichester},
publisher = {Wiley},
reportid = {PUBDB-2019-00716},
pages = {1800287},
year = {2019},
note = {© WILEY‐VCH Verlag GmbH $\&$ Co. KGaA, Weinheim},
abstract = {Ferroelectrics play an important role in various
applications, from electronics to mechanics, optics, and
biomedicine. Here, the preparation of a series of block
copolymer–templated mesostructured (lead‐free) oxide
ferroelectrics is described. Distorted perovskite LiNbO$_3$,
LiTaO$_3$, and solid solution LiNbO$_3$–LiTaO$_3$ are
produced as single‐phase thin films of good quality by the
dip‐coating method using an evaporation‐induced
self‐assembly process. They are investigated by a
combination of electron microscopy, X‐ray diffraction and
scattering, X‐ray photoelectron spectroscopy, and
time‐of‐flight secondary ion mass spectrometry. Thermal
treatment at ≥600 °C is required to initiate
crystallization. Both the pore ordering and thermal
stability increase with increasing tantalum content.
Ferroelectric testing through dynamic and remanent
polarization experiments at ambient conditions confirm the
uniformity and purity of the LiNbO$_3$ thin‐film system.
Results from positive‐up and negative‐down test
measurements reveal a stable switching polarization of 2 µC
cm$^{−2}$, with a coercive field of 50 kV cm$^{−1}$.
Taken together, the lithium niobium and tantalum oxides
prepared in the work are rare examples of sol–gel derived
perovskite‐type materials with an ordered mesoporous
morphology. Because of the spontaneous electrical
polarization observed for LiNbO$_3$, such block
copolymer–templated thin films might pave the way for the
development of a new class of 3D nanocomposite ferroics.},
cin = {DOOR},
ddc = {621.3},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
experiment = {EXP:(DE-H253)D-BW4-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000455220900020},
doi = {10.1002/aelm.201800287},
url = {https://bib-pubdb1.desy.de/record/418800},
}