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@ARTICLE{Solozhenko:418157,
      author       = {Solozhenko, Vladimir and Turkevich, Vladimir Z.},
      title        = {{P}hase {D}iagram of the {B}–{BN} {S}ystem at {P}ressures
                      up to 24 {GP}a: {E}xperimental {S}tudy and {T}hermodynamic
                      {A}nalysis},
      journal      = {The journal of physical chemistry / C},
      volume       = {122},
      number       = {15},
      issn         = {1932-7447},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PUBDB-2019-00244},
      pages        = {8505 - 8509},
      year         = {2018},
      note         = {© American Chemical Society},
      abstract     = {Phase relations in the B–BN system have been studied ex
                      situ and in situ at pressures 2–20 GPa and temperatures up
                      to 2800 K. The evolution of topology of the B–BN phase
                      diagram has been investigated up to 24 GPa using models of
                      phenomenological thermodynamics with interaction parameters
                      derived from our experimental data on phase equilibria at
                      high pressures and high temperatures. There are two
                      thermodynamically stable boron subnitrides in the system
                      i.e. B$_{13}$N$_2$ and B$_{50}$N$_2$. Above 16.5 GPa, the
                      $B_{50}N_2 ⇄ L + B_{13}N_2$ peritectic reaction transforms
                      to the solid-phase reaction of $B_{50}N_2$ decomposition
                      into tetragonal boron $(t′-B_{52})$ and B$_{13}$N$_2$,
                      while the incongruent type of B$_{13}$N$_2$ melting changes
                      to the congruent type only above 23.5 GPa. The constructed
                      phase diagram provides fundamentals for directed
                      high-pressure synthesis of superhard phases in the B–BN
                      system.},
      cin          = {DOOR},
      ddc          = {530},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {899 - ohne Topic (POF3-899)},
      pid          = {G:(DE-HGF)POF3-899},
      experiment   = {EXP:(DE-H253)D-F2.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000430896500052},
      doi          = {10.1021/acs.jpcc.8b00102},
      url          = {https://bib-pubdb1.desy.de/record/418157},
}