TY - JOUR
AU - Franke, Daniela
AU - Trots, Dmytro
AU - Vasylechko, Leonid
AU - Vashook, Vladimir
AU - Guth, Ulrich
TI - Synthesis and characterization of perovskite-type La<sub>1−y</sub>Ca<sub>y</sub>Mn<sub>1−x</sub>B<sup>″</sup><sub>x</sub>O<sub>3±δ</sub> nanomaterials (B″ = Ni, Fe; x = 0.2, 0.5; y = 0.4, 0.25)
JO - Solid state sciences
VL - 76
SN - 1293-2558
CY - Amsterdam [u.a.]
PB - Elsevier
M1 - PUBDB-2019-00205
SP - 118 - 128
PY - 2018
N1 - © Elsevier Masson SAS.
AB - Perovskite-type nanomaterials of the compositions La<sub>1−y</sub>Ca<sub>y</sub>Mn<sub>1−x</sub>B<sup>″</sup><sub>x</sub>O<sub>3±δ</sub> with B’’ = Ni, Fe; x = 0.2, 0.5 and y = 0.4, 0.25 were prepared using two different preparation routes (synthesis by precipitation and the PVA/sucrose method) at 500 °C–700 °C. The calcined products of the syntheses were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and physisorption measurements. The materials from the PVA/sucrose method contain particles with diameters from 33 nm to 48 nm, generate specific surface areas up to 33 m2/g and form pure compared to 45 nm–93 nm and up to 18 m<sup>2</sup>/g from precipitation method which contain a significant amount of sodium ions. The agglomeration process was analyzed for one nanomaterial (B’’ = Fe, x = 0.2, y = 0.4) from the PVA/sucrose method using temperature dependent XRD showing only a slight growth (4.3
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000424365800016
DO - DOI:10.1016/j.solidstatesciences.2017.12.008
UR - https://bib-pubdb1.desy.de/record/418118
ER -