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@ARTICLE{ElsayedMoussa:416542,
      author       = {Elsayed Moussa, Mehdi and Peresypkina, Eugenia and
                      Virovets, Alexandr and Venus, Dominik and Balázs, Gábor
                      and Scheer, Manfred},
      title        = {{T}uning the dimensionality of organometallic–organic
                      hybrid polymers assembled from
                      $[{C}p_{2}{M}o_{2}({CO})_{4}(η^{2}-{P}_{2})]$, bipyridyl
                      linkers and ${A}g^{{I}}$ ions},
      journal      = {CrystEngComm},
      volume       = {20},
      number       = {46},
      issn         = {1466-8033},
      address      = {London},
      publisher    = {RSC},
      reportid     = {PUBDB-2018-04954},
      pages        = {7417 - 7422},
      year         = {2018},
      note         = {© The Royal Society of Chemistry},
      abstract     = {The reactions of the P$_2$ ligand complex
                      [Cp$_2$Mo$_2$(CO)$_4$($η^2$-P$_2$)] (Cp =C$_5$H$_5$, 1)
                      with Ag[Al{OC(CF$_3$)$_3$}$_4$] (Ag[TEF]) in the presence of
                      therigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3),
                      4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and
                      4,4′-bipyridine (5) possessingvarious lengths are studied.
                      The reaction with the longer linkers (3and 4) leads to the
                      formation of the 1D organometallic–organichybrid polymers
                      [{Cp$_2$Mo$_2$(CO)$_4$($μ_4$,$η^{1:1:2:2}$-P$_2$)}$_2${Cp$_2$Mo$_2$(CO)$_4$($μ_3$,$η^{1:2:2}$-$P_2$)}$_2$($μ,η^{1:1}$-C$_{12}$H$_8$N$_2$)Ag$_2$]$_n$[TEF]$_{2n}$
                      (6)
                      and[{Cp$_2$Mo$_2$(CO)$_4$($μ_4$,$η^{1:1:2:2}$-P$_2$)}$_2${Cp$_2$Mo$_2$(CO)$_4$($μ_3$,$η^{1:2:2}$-P$_2$)}$_2$($μ,η^{1:1}$-C$_{26}$H$_{16}$N$_2$)Ag$_2$]$_n$[TEF]$_{2n}$
                      (7) in high selectivity. A similar reaction withthe short
                      linker 5 affords a mixture of the 2D hybrid
                      polymers[{Cp$_2$Mo$_2$(CO)$_4$($μ_4$,$η^{1:2:2:2}$-P$_2$)}$_2$($μ,η^{1:1}$-C$_{13}$H$_{14}$N$_2$)Ag$_2$]$_n$[TEF]$_{2n}$
                      (8) andthe 3D hybrid network
                      [{Cp$_2$Mo$_2$(CO)$_4$($μ_4$,$η^{1:1:2:2}$-P$_2$)}$_2$($μ,η^{1:1}$-C$_{10}$H$_8$N$_2$)Ag]$_n$[TEF]$_{2n}$
                      (9). However, a selective synthesis of 8 or 9 ispossible
                      when the reaction is performed at 0 °C and 60
                      °C,respectively.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (POF3-622) / FS-Proposal: I-20160654
                      (I-20160654)},
      pid          = {G:(DE-HGF)POF3-6G3 / G:(DE-H253)I-20160654},
      experiment   = {EXP:(DE-H253)P-P11-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000451535200002},
      doi          = {10.1039/C8CE01792A},
      url          = {https://bib-pubdb1.desy.de/record/416542},
}