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001     401870
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100 1 _ |a Jonane, Inga
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245 _ _ |a X-ray absorption near edge spectroscopy of thermochromic phase transition in CuMoO$_4$
260 _ _ |a College Park, Md.
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520 _ _ |a Thermochromic phase transition was studied in CuMoO4 using the Cu and Mo K-edge x-ray absorption spec-troscopy in the temperature range of 10–300 K. The hysteretic behavior has been evidenced from the tempera-ture dependence of the pre-edge shoulder intensity at the Mo K-edge, indicating that the transition from brownish-red γ-CuMoO$_4$ to green α-CuMoO$_4$ occurs in the temperature range of 230–280 K upon heating, whereas the α-to-γ transition occurs between 200 and 120 K upon cooling. Such behavior of the pre-edge shoulder at the Mo K-edge correlates with the change of molybdenum coordination between distorted tetrahedral in α-CuMoO4 and distorted octahedral in γ-CuMoO$_4$. This result has been supported by ab initio full-multiple-scattering x-ray absorption near edge structure (XANES) calculations.
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700 1 _ |a Cintins, Arturs
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700 1 _ |a Kalinko, Aleksandr
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700 1 _ |a Chernikov, Roman
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700 1 _ |a Kuzmin, Alexei
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773 _ _ |a 10.1063/1.5034155
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