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@ARTICLE{Sentker:400110,
author = {Sentker, Kathrin and Zantop, Arne W. and Lippmann, Milena
and Hofmann, Tommy and Seeck, Oliver and Kityk, Andriy V.
and Yildirim, Arda and Schönhals, Andreas and Mazza, Marco
G. and Huber, Patrick},
title = {{Q}uantized {S}elf-{A}ssembly of {D}iscotic {R}ings in a
{L}iquid {C}rystal {C}onfined in {N}anopores},
journal = {Physical review letters},
volume = {120},
number = {6},
issn = {1079-7114},
address = {College Park, Md.},
publisher = {APS},
reportid = {PUBDB-2018-01139},
pages = {067801},
year = {2018},
abstract = {Disklike molecules with aromatic cores spontaneously stack
up in linear columns with high, one-dimensional charge
carrier mobilities along the columnar axes, making them
prominent model systems for functional, self-organized
matter. We show by high-resolution optical birefringence and
synchrotron-based x-ray diffraction that confining a
thermotropic discotic liquid crystal in cylindrical
nanopores induces a quantized formation of annular layers
consisting of concentric circular bent columns, unknown in
the bulk state. Starting from the walls this ring
self-assembly propagates layer by layer towards the pore
center in the supercooled domain of the bulk
isotropic-columnar transition and thus allows one to switch
on and off reversibly single, nanosized rings through small
temperature variations. By establishing a Gibbs free energy
phase diagram we trace the phase transition quantization to
the discreteness of the layers’ excess bend deformation
energies in comparison to the thermal energy, even for this
near room-temperature system. Monte Carlo simulations
yielding spatially resolved nematic order parameters,
density maps, and bond-orientational order parameters
corroborate the universality and robustness of the
confinement-induced columnar ring formation as well as its
quantized nature.},
cin = {DOOR / FS-PE / FS-TI},
ddc = {550},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PE-20120731 /
I:(DE-H253)FS-TI-20120731},
pnm = {6214 - Nanoscience and Materials for Information Technology
(POF3-621) / 6G3 - PETRA III (POF3-622)},
pid = {G:(DE-HGF)POF3-6214 / G:(DE-HGF)POF3-6G3},
experiment = {EXP:(DE-H253)P-P08-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:29481274},
UT = {WOS:000424092100010},
doi = {10.1103/PhysRevLett.120.067801},
url = {https://bib-pubdb1.desy.de/record/400110},
}