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@ARTICLE{Dicke:399573,
      author       = {Dicke, B. and Hoffmann, A. and Stanek, J. and Rampp, M. S.
                      and Grimm-Lebsanft, Benjamin and Biebl, F. and Rukser, D.
                      and Maerz, B. and Göries, D. and Naumova, M. and Biednov,
                      M. and Neuber, G. and Wetzel, A. and Hofmann, S. M. and
                      Roedig, P. and Meents, A. and Bielecki, J. and Andreasson,
                      J. and Beyerlein, K. R. and Chapman, H. N. and Bressler, C.
                      and Zinth, W. and Rübhausen, M. and Herres-Pawlis, S.},
      title        = {{T}ransferring the entatic-state principle to copper
                      photochemistry},
      journal      = {Nature chemistry},
      volume       = {10},
      issn         = {1755-4349},
      address      = {London},
      publisher    = {Nature Publishing Group},
      reportid     = {PUBDB-2018-00754},
      pages        = {355 – 362},
      year         = {2018},
      note         = {© Macmillan Publishers Limited, part of Springer Nature},
      abstract     = {The entatic state denotes a distorted coordination geometry
                      of a complex from its typical arrangement that generates an
                      improvement to its function. The entatic-state principle has
                      been observed to apply to copper electron-transfer proteins
                      and it results in a lowering of the reorganization energy of
                      the electron-transfer process. It is thus crucial for a
                      multitude of biochemical processes, but its importance to
                      photoactive complexes is unexplored. Here we study a copper
                      complex—with a specifically designed constraining ligand
                      geometry—that exhibits metal-to-ligand charge-transfer
                      state lifetimes that are very short. The
                      guanidine–quinoline ligand used here acts on the
                      bis(chelated) copper(I) centre, allowing only small
                      structural changes after photoexcitation that result in very
                      fast structural dynamics. The data were collected using a
                      multimethod approach that featured time-resolved
                      ultraviolet–visible, infrared and X-ray absorption and
                      optical emission spectroscopy. Through supporting density
                      functional calculations, we deliver a detailed picture of
                      the structural dynamics in the picosecond-to-nanosecond time
                      range.},
      cin          = {DOOR ; HAS-User / CFEL-AO / FS-ATTO / FS-PS / FS-CFEL-1 /
                      Eur.XFEL},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)CFEL-AO-20160914
                      / I:(DE-H253)FS-ATTO-20170403 / I:(DE-H253)FS-PS-20131107 /
                      I:(DE-H253)FS-CFEL-1-20120731 /
                      $I:(DE-H253)Eur_XFEL-20120731$},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G3 - PETRA III (POF3-622) / SWEDEN-DESY - SWEDEN-DESY
                      Collaboration $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G3 /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P11-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29461525},
      UT           = {WOS:000425589000018},
      doi          = {10.1038/nchem.2916},
      url          = {https://bib-pubdb1.desy.de/record/399573},
}