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@ARTICLE{Kappen:398991,
      author       = {Kappen, Peter and Ferrando-Miguel, G. and Reichman, S. M.
                      and Innes, L. and Welter, E. and Pigram, P. J.},
      title        = {{A}ntimony leaching and chemical species analyses in an
                      industrial solid waste: {S}urface and bulk speciation using
                      {T}o{F}-{SIMS} and {XANES}},
      journal      = {Journal of hazardous materials},
      volume       = {329},
      issn         = {0304-3894},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2018-00308},
      pages        = {131 - 140},
      year         = {2017},
      note         = {(c) Elsevier ; Post referee fulltext in progress; Embargo
                      12 months from publication},
      abstract     = {The surface chemistry and bulk chemical speciation of solid
                      industrial wastes containing 8 $wt-\%$ antimony (Sb) were
                      investigated using synchrotron X-ray Absorption Near Edge
                      Structure (XANES) and Time-of-Flight Ion Secondary Mass
                      Spectrometry (ToF-SIMS). Leaching experiments were conducted
                      in order to better understand the behavior of Sb in waste
                      streams and to inform regulatory management of
                      antimony-containing wastes. The experiments also demonstrate
                      how a combination of XANES and ToF-SIMS adds value to the
                      field of waste investigations. Leaching treatments (acid and
                      base) were performed at a synchrotron over 24 h time
                      periods. Surface analyses of the wastes before leaching
                      showed the presence of Sb associated with S and O. Bulk
                      analyses revealed Sb to be present, primarily, as trivalent
                      sulfide species. Both acid and base leaching did not change
                      the antimony speciation on the solid. Leaching transferred
                      about $1\%$ of the total Sb into solution where Sb was found
                      to be present as Sb(V). XANES data showed similarities
                      between leachate and FeSbO$_4$. During base leaching, the Sb
                      content in solution gradually increased over time, and
                      potential desorption mechanisms are discussed.},
      cin          = {DOOR / FS-PEX},
      ddc          = {530},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PEX-20130206},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-H253)D-C-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:28131040},
      UT           = {WOS:000396950700015},
      doi          = {10.1016/j.jhazmat.2017.01.022},
      url          = {https://bib-pubdb1.desy.de/record/398991},
}