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@ARTICLE{Pospiech:398580,
      author       = {Pospiech, Doris and Jehnichen, Dieter and Eckstein, Kathrin
                      and Scheibe, Philipp and Komber, Hartmut and Sahre, Karin
                      and Janke, Andreas and Reuter, Uta and Häußler, Liane and
                      Schellkopf, Leonard and Friedel, Peter and Voit, Brigitte},
      title        = {{S}emifluorinated {PMMA} {B}lock {C}opolymers: {S}ynthesis,
                      {N}anostructure, and {T}hin {F}ilm {P}roperties},
      journal      = {Macromolecular chemistry and physics},
      volume       = {218},
      number       = {18},
      issn         = {1022-1352},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2017-14140},
      pages        = {1600599 -},
      year         = {2017},
      note         = {© WILEY-VCH Verlag GmbH $\&$ Co. KGaA, Weinheim ; Post
                      referee fulltext in progress; Embargo 12 months from
                      publication},
      abstract     = {Diblock copolymers (BCP) with poly(methyl methacrylate) and
                      poly(1H,1H,2H,2H-perfluorodecyl methacrylate) (PsfMA) blocks
                      prepared by anionic polymerization in tetrahydrofuran at
                      −78 °C and atom transfer radical polymerization (ATRP) at
                      60 °C, respectively, with stepwise varied composition over
                      a wide range in the phase diagram are compared with respect
                      to synthesis limits, phase separation behavior in bulk, and
                      properties of thin films. Both methods yield BCPs with low
                      dispersity (1.1–1.2) at molar masses below 100 kg
                      mol$^{−1}$. Higher semifluorinated contents can be
                      achieved by ATRP in 1,3-bis(trifluoromethyl)benzene which
                      ensured solubility of PsfMA. BCPs obtained by anionic
                      polymerization show a more distinct phase separation, that
                      is, more regular nanostructures. Additionally,
                      self-organization of the semifluorinated side chains occurs
                      generating smectic layers which alters in turn the BCP
                      morphology especially in thin films as compared to
                      non-semifluorinated BCP. All BCPs show amphiphilic behavior
                      and form micelles in organic solvents which can be used to
                      deposit nanoparticles.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {899 - ohne Topic (POF3-899)},
      pid          = {G:(DE-HGF)POF3-899},
      experiment   = {EXP:(DE-H253)D-A2-20150101 / EXP:(DE-H253)D-BW4-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000410949100009},
      doi          = {10.1002/macp.201600599},
      url          = {https://bib-pubdb1.desy.de/record/398580},
}