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000398580 1001_ $$0P:(DE-H253)PIP1009157$$aPospiech, Doris$$b0$$eCorresponding author
000398580 245__ $$aSemifluorinated PMMA Block Copolymers: Synthesis, Nanostructure, and Thin Film Properties
000398580 260__ $$aWeinheim$$bWiley-VCH$$c2017
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000398580 500__ $$a© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim ; Post referee fulltext in progress; Embargo 12 months from publication
000398580 520__ $$aDiblock copolymers (BCP) with poly(methyl methacrylate) and poly(1H,1H,2H,2H-perfluorodecyl methacrylate) (PsfMA) blocks prepared by anionic polymerization in tetrahydrofuran at −78 °C and atom transfer radical polymerization (ATRP) at 60 °C, respectively, with stepwise varied composition over a wide range in the phase diagram are compared with respect to synthesis limits, phase separation behavior in bulk, and properties of thin films. Both methods yield BCPs with low dispersity (1.1–1.2) at molar masses below 100 kg mol$^{−1}$. Higher semifluorinated contents can be achieved by ATRP in 1,3-bis(trifluoromethyl)benzene which ensured solubility of PsfMA. BCPs obtained by anionic polymerization show a more distinct phase separation, that is, more regular nanostructures. Additionally, self-organization of the semifluorinated side chains occurs generating smectic layers which alters in turn the BCP morphology especially in thin films as compared to non-semifluorinated BCP. All BCPs show amphiphilic behavior and form micelles in organic solvents which can be used to deposit nanoparticles.
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000398580 7001_ $$0P:(DE-H253)PIP1008006$$aJehnichen, Dieter$$b1
000398580 7001_ $$0P:(DE-HGF)0$$aEckstein, Kathrin$$b2
000398580 7001_ $$aScheibe, Philipp$$b3
000398580 7001_ $$aKomber, Hartmut$$b4
000398580 7001_ $$aSahre, Karin$$b5
000398580 7001_ $$0P:(DE-H253)PIP1002362$$aJanke, Andreas$$b6
000398580 7001_ $$aReuter, Uta$$b7
000398580 7001_ $$aHäußler, Liane$$b8
000398580 7001_ $$aSchellkopf, Leonard$$b9
000398580 7001_ $$0P:(DE-H253)PIP1007994$$aFriedel, Peter$$b10
000398580 7001_ $$aVoit, Brigitte$$b11
000398580 773__ $$0PERI:(DE-600)1475026-0$$a10.1002/macp.201600599$$gVol. 218, no. 18, p. 1600599 -$$n18$$p1600599 -$$tMacromolecular chemistry and physics$$v218$$x1022-1352$$y2017
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