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@ARTICLE{Pospiech:398577,
author = {Pospiech, Doris and Jehnichen, Dieter and Starke, Sandra
and Müller, Felix Johannes and Bünker, Tobias and
Wollenberg, Anne and Häußler, Liane and Simon, Frank and
Grundke, Karina and Oertel, Ulrich and Opitz, Michael and
Kruspe, Rainer},
title = {{M}ultifunctional methacrylate-based coatings for glass and
metal surfaces},
journal = {Applied surface science},
volume = {399},
issn = {0169-4332},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {PUBDB-2017-14137},
pages = {205 - 214},
year = {2017},
abstract = {In order to prevent freshwater biofouling glass and metal
surfaces were coated with novel transparent
methacrylate-based copolymers. The multifunctionality of the
copolymers, such as adhesion to the substrate, surface
polarity, mechanical long-term stability in water, and
ability to form metal complexes was inserted by the choice
of suitable comonomers. The monomer 2-acetoacetoxy ethyl
methacrylate (AAMA) was used as complexing unit to produce
copper(II) complexes in the coating’s upper surface layer.
The semifluorinated monomer 1H,1H,2H,2H-perfluorodecyl
methacrylate was employed to adjust the surface polarity and
wettability. Comprehensive surface characterization
techniques, such as X-ray photoelectron spectroscopy (XPS)
and contact angle measurements showed that surface
compositions and properties can be easily adjusted by
varying the concentrations of the comonomers. The formation
of copper(II) complexes along the copolymer chains and their
stability against washing out with plenty of water was
proven by XPS. Copolymers containing semifluorinated
comonomers significantly inhibited the growth of
Achnanthidium species. Copolymers with copper-loaded
AAMA-sequences were able to reduce both the growth of
Achnanthidium spec. and Staphylococcus aureus.},
cin = {DOOR},
ddc = {670},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
experiment = {EXP:(DE-H253)D-A2-20150101 / EXP:(DE-H253)D-BW4-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000393001700023},
doi = {10.1016/j.apsusc.2016.12.018},
url = {https://bib-pubdb1.desy.de/record/398577},
}