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@MISC{Raabe:396846,
author = {Raabe, Dierk and Zhang, Jian},
title = {{G}um metals pave the way for new applications},
reportid = {PUBDB-2017-12926},
year = {2017},
abstract = {Metals which can be bent as gum pave the way for new
industrial applications for example in the aerospace
industry. These so-called gum metals exist but the mechanism
behind this behaviour was still unsettled and thus difficult
to be used for applications. Scientists from the
Max-Planck-Institut für Eisenforschung (MPIE) in
Düsseldorf have observed a new phase transformation in a
titanium alloy that could further our understanding of
exactly this behaviour whereby the term “phase” refers
to the crystal structure in which the atoms are arranged.The
material scientists of the MPIE used X-rays to reveal the
inner structure of a special alloy consisting of titanium,
niobium, tantalum and zirconium. This titanium alloy
displays some unusual mechanical properties under mechanical
stress: “On being deformed, it does not become harder or
brittle, the way metals usually do, but instead it bends,
almost like honey. In scientific terms, it has a very low
elastic stiffness and very high ductility,” explains Dierk
Raabe, director at the MPIE.This makes the alloy extremely
attractive for various industrial applications. In the
aerospace industry, for example, it can be used as a kind of
crash absorber. “When an aircraft’s turbine is damaged
by hail or a bird strike, there is a risk that individual
parts may shatter and damage the fuselage too. If parts of
the protective casing around a turbine were made of this
type of gum metal, they could capture the flying debris
because the impact would not destroy but only deform
them,” says Raabe.The researchers have revealed
peculiarities in its nanostructure using various techniques
like X-rays, transmission electron microscopy and atom probe
tomography. Titanium alloys normally occur in two different
phases. At room temperature, the atoms are usually found in
the so-called alpha phase, at high temperatures they switch
to the beta phase. The metals display different properties,
depending on which phase they occur in. Gum metals primarily
consist of the beta phase, which is stable at room
temperature in the case of these alloys.With the help of
X-rays at the accelerator centre DESY the Max Planck
scientists were able to analyse the crystal structure of the
alloy during the transition. “When you shine X-rays onto a
sample, the radiation is reflected by the crystal lattice.
This produces a distinct pattern of reflections, a so-called
diffractogram, from which we are able to deduce the relative
positions of the atoms, in other words the crystal structure
that they adopt,” explains Ann-Christin Dippel, who was in
charge of the X-rays experiments at the DESY measuring
station.This way the researchers at the MPIE have discovered
a new mechanism during the phase transformation. The team of
Jian Zhang has observed a new structure, which forms when
the beta phase is transformed into the alpha phase: the
omega phase. If the beta phase is cooled down rapidly from a
high temperature, some of the atoms change position to adopt
the energetically more favourable arrangement of the alpha
phase. The movements of these atoms lead to mechanical
stress along the phase boundary, almost as if the different
phases were tugging on each other. When this stress exceeds
a critical value, a new arrangement is adopted, the
so-called omega phase. “This newly discovered structure
only arises when sheer stress is generated at the phase
boundary, and it facilitates the transformation of the alpha
into the beta phase. It can only exist between two other
phases because it is stabilised by them,” reports Raabe.
When the stress drops below the critical value because of
the new layer, a new alpha phase layer is formed bordering
on an omega phase. This results in a microstructure
consisting of lots of layers, some of them on an atomic
scale, each having a different structure. This transition
also occurs when static forces are applied and is completely
reversible. The scientists are now hoping that the newly
discovered structure will help them to better understand the
properties of this material and later to develop new,
improved varieties of titanium alloys.},
cin = {DOOR / FS-PE},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PE-20120731},
pnm = {6G3 - PETRA III (POF3-622)},
pid = {G:(DE-HGF)POF3-6G3},
experiment = {EXP:(DE-H253)P-P02.1-20150101},
typ = {PUB:(DE-HGF)21},
doi = {10.3204/PUBDB-2017-12926},
url = {https://bib-pubdb1.desy.de/record/396846},
}