guest ::
| Home > Publications database > Cyclic stability and structure of nanoconfined Ti-doped $\mathrm{NaAlH_{4}}$ > print |
| Home > Publications database > Cyclic stability and structure of nanoconfined Ti-doped $\mathrm{NaAlH_{4}}$ > print |
| 001 | 312128 | ||
| 005 | 20250730111317.0 | ||
| 024 | 7 | _ | |a 10.1016/j.ijhydene.2015.12.185 |2 doi |
| 024 | 7 | _ | |a 0360-3199 |2 ISSN |
| 024 | 7 | _ | |a 1879-3487 |2 ISSN |
| 024 | 7 | _ | |a WOS:000372378100009 |2 WOS |
| 024 | 7 | _ | |a openalex:W2254658001 |2 openalex |
| 037 | _ | _ | |a PUBDB-2016-05317 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 660 |
| 100 | 1 | _ | |a Paskevicius, Mark |0 P:(DE-H253)PIP1023987 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Cyclic stability and structure of nanoconfined Ti-doped $\mathrm{NaAlH_{4}}$ |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2016 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1519140098_3118 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 500 | _ | _ | |a (c) Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. Post referee full text in progress (embargo 1 year from 1 February 2016). |
| 520 | _ | _ | |a NaAlH4 was melt infiltrated within a CO$_2$ activated carbon aerogel, which had been preloaded with TiCl$_3$. Nanoconfinement was verified by Small Angle X-Ray Scattering (SAXS) and the nature of the Ti was investigated with Anomalous SAXS (ASAXS) and X-Ray Absorption Near Edge Structure (XANES) to determine its size and chemical state. The Ti is found to be in a similar state to that found in the bulk Ti-doped NaAlH$_4$ system where it exists as Al$_{1−x}$Ti$_x$ nanoalloys. Crystalline phases exist within the carbon aerogel pores, which are analysed by in-situ Powder X-Ray Diffraction (PXD) during hydrogen cycling. The in-situ data reveals that the hydrogen release from NaAlH$_4$ and its hydrogen uptake occurs through the Na$_3$AlH$_6$ intermediate when confined at this size scale. The hydrogen capacity from the nanoconfined NaAlH$_4$ is found to initially be much higher in this CO$_2$ activated aerogel compared with previous studies into unactivated aerogels. |
| 536 | _ | _ | |a 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) |0 G:(DE-HGF)POF3-6213 |c POF3-621 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 693 | _ | _ | |a DORIS III |f DORIS Beamline A1 |1 EXP:(DE-H253)DORISIII-20150101 |0 EXP:(DE-H253)D-A1-20150101 |6 EXP:(DE-H253)D-A1-20150101 |x 0 |
| 700 | 1 | _ | |a Filsø, Uffe |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Karimi, Fahim |0 P:(DE-H253)PIP1008662 |b 2 |
| 700 | 1 | _ | |a Puszkiel, Julián |0 P:(DE-H253)PIP1013727 |b 3 |
| 700 | 1 | _ | |a Pranzas, Philipp Klaus |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Pistidda, Claudio |0 P:(DE-H253)PIP1010848 |b 5 |
| 700 | 1 | _ | |a Hoell, Armin |0 P:(DE-H253)PIP1008173 |b 6 |
| 700 | 1 | _ | |a Welter, Edmund |0 P:(DE-H253)PIP1001273 |b 7 |
| 700 | 1 | _ | |a Schreyer, Andreas |0 P:(DE-H253)PIP1006650 |b 8 |
| 700 | 1 | _ | |a Klassen, Thomas |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Dornheim, Martin |0 P:(DE-H253)PIP1009603 |b 10 |
| 700 | 1 | _ | |a Jensen, Torben R. |0 P:(DE-HGF)0 |b 11 |
| 773 | _ | _ | |a 10.1016/j.ijhydene.2015.12.185 |g Vol. 41, no. 7, p. 4159 - 4167 |0 PERI:(DE-600)1484487-4 |n 7 |p 4159 - 4167 |t International journal of hydrogen energy |v 41 |y 2016 |x 0360-3199 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/312128/files/10.1016_j.ijhydene.2015.12.185.pdf |y Restricted |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/312128/files/10.1016_j.ijhydene.2015.12.185.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/312128/files/10.1016_j.ijhydene.2015.12.185.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/312128/files/10.1016_j.ijhydene.2015.12.185.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/312128/files/10.1016_j.ijhydene.2015.12.185.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 909 | C | O | |p VDB |o oai:bib-pubdb1.desy.de:312128 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 0 |6 P:(DE-H253)PIP1023987 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 2 |6 P:(DE-H253)PIP1008662 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 3 |6 P:(DE-H253)PIP1013727 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 5 |6 P:(DE-H253)PIP1010848 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 6 |6 P:(DE-H253)PIP1008173 |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 7 |6 P:(DE-H253)PIP1001273 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 8 |6 P:(DE-H253)PIP1006650 |
| 910 | 1 | _ | |a Externes Institut |0 I:(DE-HGF)0 |k Extern |b 10 |6 P:(DE-H253)PIP1009603 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF3-620 |0 G:(DE-HGF)POF3-621 |2 G:(DE-HGF)POF3-600 |v In-house research on the structure, dynamics and function of matter |9 G:(DE-HGF)POF3-6213 |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |
| 914 | 1 | _ | |y 2016 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b INT J HYDROGEN ENERG : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-H253)HAS-User-20120731 |k DOOR |l DOOR-User |x 0 |
| 920 | 1 | _ | |0 I:(DE-H253)FS-PEX-20130206 |k FS-PEX |l PETRA III Extension |x 1 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-H253)HAS-User-20120731 |
| 980 | _ | _ | |a I:(DE-H253)FS-PEX-20130206 |
| 980 | _ | _ | |a UNRESTRICTED |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|