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@ARTICLE{Paskevicius:312128,
      author       = {Paskevicius, Mark and Filsø, Uffe and Karimi, Fahim and
                      Puszkiel, Julián and Pranzas, Philipp Klaus and Pistidda,
                      Claudio and Hoell, Armin and Welter, Edmund and Schreyer,
                      Andreas and Klassen, Thomas and Dornheim, Martin and Jensen,
                      Torben R.},
      title        = {{C}yclic stability and structure of nanoconfined {T}i-doped
                      $\mathrm{{N}a{A}l{H}_{4}}$},
      journal      = {International journal of hydrogen energy},
      volume       = {41},
      number       = {7},
      issn         = {0360-3199},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2016-05317},
      pages        = {4159 - 4167},
      year         = {2016},
      note         = {(c) Hydrogen Energy Publications, LLC. Published by
                      Elsevier Ltd. Post referee full text in progress (embargo 1
                      year from 1 February 2016).},
      abstract     = {NaAlH4 was melt infiltrated within a CO$_2$ activated
                      carbon aerogel, which had been preloaded with TiCl$_3$.
                      Nanoconfinement was verified by Small Angle X-Ray Scattering
                      (SAXS) and the nature of the Ti was investigated with
                      Anomalous SAXS (ASAXS) and X-Ray Absorption Near Edge
                      Structure (XANES) to determine its size and chemical state.
                      The Ti is found to be in a similar state to that found in
                      the bulk Ti-doped NaAlH$_4$ system where it exists as
                      Al$_{1−x}$Ti$_x$ nanoalloys. Crystalline phases exist
                      within the carbon aerogel pores, which are analysed by
                      in-situ Powder X-Ray Diffraction (PXD) during hydrogen
                      cycling. The in-situ data reveals that the hydrogen release
                      from NaAlH$_4$ and its hydrogen uptake occurs through the
                      Na$_3$AlH$_6$ intermediate when confined at this size scale.
                      The hydrogen capacity from the nanoconfined NaAlH$_4$ is
                      found to initially be much higher in this CO$_2$ activated
                      aerogel compared with previous studies into unactivated
                      aerogels.},
      cin          = {DOOR / FS-PEX},
      ddc          = {660},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PEX-20130206},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-H253)D-A1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000372378100009},
      doi          = {10.1016/j.ijhydene.2015.12.185},
      url          = {https://bib-pubdb1.desy.de/record/312128},
}