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000312128 1001_ $$0P:(DE-H253)PIP1023987$$aPaskevicius, Mark$$b0$$eCorresponding author
000312128 245__ $$aCyclic stability and structure of nanoconfined Ti-doped $\mathrm{NaAlH_{4}}$
000312128 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2016
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000312128 500__ $$a(c) Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. Post referee full text in progress (embargo 1 year from 1 February 2016).
000312128 520__ $$aNaAlH4 was melt infiltrated within a CO$_2$ activated carbon aerogel, which had been preloaded with TiCl$_3$. Nanoconfinement was verified by Small Angle X-Ray Scattering (SAXS) and the nature of the Ti was investigated with Anomalous SAXS (ASAXS) and X-Ray Absorption Near Edge Structure (XANES) to determine its size and chemical state. The Ti is found to be in a similar state to that found in the bulk Ti-doped NaAlH$_4$ system where it exists as Al$_{1−x}$Ti$_x$ nanoalloys. Crystalline phases exist within the carbon aerogel pores, which are analysed by in-situ Powder X-Ray Diffraction (PXD) during hydrogen cycling. The in-situ data reveals that the hydrogen release from NaAlH$_4$ and its hydrogen uptake occurs through the Na$_3$AlH$_6$ intermediate when confined at this size scale. The hydrogen capacity from the nanoconfined NaAlH$_4$ is found to initially be much higher in this CO$_2$ activated aerogel compared with previous studies into unactivated aerogels.
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000312128 7001_ $$0P:(DE-HGF)0$$aFilsø, Uffe$$b1
000312128 7001_ $$0P:(DE-H253)PIP1008662$$aKarimi, Fahim$$b2
000312128 7001_ $$0P:(DE-H253)PIP1013727$$aPuszkiel, Julián$$b3
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000312128 773__ $$0PERI:(DE-600)1484487-4$$a10.1016/j.ijhydene.2015.12.185$$gVol. 41, no. 7, p. 4159 - 4167$$n7$$p4159 - 4167$$tInternational journal of hydrogen energy$$v41$$x0360-3199$$y2016
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