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@INPROCEEDINGS{Pienack:311595,
      author       = {Pienack, Nicole and Terraschke, Huayna and Bensch,
                      Wolfgang},
      title        = {{I}n-situ {C}rystallization {C}ell: {D}evelopments and
                      {F}irst {R}esults of the {M}odel {S}ystem ${A}l(acac)_{3}$},
      reportid     = {PUBDB-2016-04905},
      year         = {2016},
      abstract     = {In-situ investigations of the crystallization of solids are
                      still necessary for the understanding and the rational
                      synthesis of precursors, intermediates and products with
                      special or even improved properties.[1] With our
                      crystallization cell,[2] the detection and the control of
                      different reaction parameters during chemical reactions in
                      fluid media can be achieved. The modifications of the cell
                      allow in-situ experiments with X-ray diffraction (XRD).[2]
                      The crystallization of Al(acac)3 (acac = acetylacetonate) as
                      model system was investigated to demonstrate the performance
                      of the cell. First in-situ energy-dispersive X-ray
                      diffraction (EDXRD) experiments were carried out at the
                      beamline F3 (DORIS, DESY). During the crystallization of
                      Al(acac)3 changes of pH value and redox potential could be
                      observed, but a higher concentrated reaction suspension was
                      required for obtaining suitable EDXRD spectra. In subsequent
                      in-situ XRD experiments at beamline P07B (PETRA III, DESY)
                      with modified reaction vessels in a special sample holder
                      (Fig. 1) the growth of the Bragg peaks during the
                      crystallization of Al(acac)3 could be detected. The
                      possibility of integrating further methods and/or sensors is
                      highly important while working with synchrotron radiation
                      (Fig. 1). Hence, the potential of the cell was proved to be
                      beneficial for controlling and monitoring several reaction
                      parameters during the crystallization.},
      month         = {Sep},
      date          = {2016-09-19},
      organization  = {18. Conference of the GDCh Division
                       Solid State Chemistry and Materials
                       Research, Innsbruck (Austria), 19 Sep
                       2016 - 21 Sep 2016},
      cin          = {DOOR},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (POF3-622)},
      pid          = {G:(DE-HGF)POF3-6G3},
      experiment   = {EXP:(DE-H253)D-F3-20150101 / EXP:(DE-H253)P-P07-20150101 /
                      EXP:(DE-H253)P-P09-20150101},
      typ          = {PUB:(DE-HGF)1},
      url          = {https://bib-pubdb1.desy.de/record/311595},
}