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@ARTICLE{Parker:299815,
      author       = {Parker, Stewart F. and Adroja, Devashibhai and
                      Jiménez-Ruiz, Mónica and Tischer, Markus and Möbus,
                      Konrad and Wieland, Stefan D. and Albers, Peter},
      title        = {{C}haracterisation of the surface of freshly prepared
                      precious metal catalysts},
      journal      = {Physical chemistry, chemical physics},
      volume       = {18},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PUBDB-2016-02027},
      pages        = {17196-17201},
      year         = {2016},
      abstract     = {A combination of electron microscopy, X-ray and neutron
                      spectroscopies and computational methods has provided new
                      insights into the species present on the surface of freshly
                      prepared precious metal catalysts. The results show that in
                      all cases, at least half of the surface is metallic or
                      nearly so, with the remainder covered by oxygen, largely as
                      hydroxide. Water is also present and is strongly held; weeks
                      of pumping under high vacuum is insufficient to remove it.
                      The hydroxyls are reactive as shown by their reaction with
                      or displacement by CO and can be removed by hydrogenation.
                      This clearly has implications for how precious metal
                      catalysts are activated after preparation.},
      cin          = {FS-US},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-US-20120731},
      pnm          = {6214 - Nanoscience and Materials for Information Technology
                      (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6214},
      experiment   = {EXP:(DE-H253)D-E4-20150101 / EXP:(DE-H253)D-X1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000379482100007},
      pubmed       = {pmid:26986759},
      doi          = {10.1039/C6CP01027J},
      url          = {https://bib-pubdb1.desy.de/record/299815},
}