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@ARTICLE{Karimi:293591,
      author       = {Karimi, Fahim and Klaus Pranzas, P. and Pistidda, Claudio
                      and Puszkiel, Julián A. and Milanese, Chiara and Vainio,
                      Ulla and Paskevicius, Mark and Emmler, Thomas and Santoru,
                      Antonio and Utke, Rapee and Tolkiehn, Martin and Minella,
                      Christian B. and Chaudhary, Anna-Lisa and Boerries, Stefan
                      and Buckley, Craig E. and Enzo, Stefano and Schreyer,
                      Andreas and Klassen, Thomas and Dornheim, Martin},
      title        = {{S}tructural and kinetic investigation of the hydride
                      composite $\mathrm{{C}a({BH}_{4})_{2} + {M}g{H}_2}$ system
                      doped with $\mathrm{{N}b{F}_5}$ for solid-state hydrogen
                      storage},
      journal      = {Physical chemistry, chemical physics},
      volume       = {17},
      number       = {41},
      issn         = {1463-9084},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PUBDB-2016-00654},
      pages        = {27328 - 27342},
      year         = {2015},
      abstract     = {Designing safe, compact and high capacity hydrogen storage
                      systems is the key step towards introducing a pollutant free
                      hydrogen technology into a broad field of applications. Due
                      to the chemical bonds of hydrogen–metal atoms, metal
                      hydrides provide high energy density in safe hydrogen
                      storage media. Reactive hydride composites (RHCs) are a
                      promising class of high capacity solid state hydrogen
                      storage systems. Ca(BH$_4$)$_2$ + MgH$_2$ with a hydrogen
                      content of 8.4 wt\% is one of the most promising members of
                      the RHCs. However, its relatively high desorption
                      temperature of ∼350 °C is a major drawback to meeting the
                      requirements for practical application. In this work, by
                      using NbF5 as an additive, the dehydrogenation temperature
                      of this RHC was significantly decreased. To elucidate the
                      role of NbF5 in enhancing the desorption properties of the
                      Ca(BH$_4$)$_2$ + MgH$_2$ (Ca-RHC), a comprehensive
                      investigation was carried out via manometric measurements,
                      mass spectrometry, Differential Scanning Calorimetry (DSC),
                      in situ Synchrotron Radiation-Powder X-ray Diffraction
                      (SR-PXD), X-ray Absorption Spectroscopy (XAS), Anomalous
                      Small-Angle X-ray Scattering (ASAXS), Scanning and
                      Transmission Electron Microscopy (SEM, TEM) and Nuclear
                      Magnetic Resonance (NMR) techniques.},
      cin          = {FS-DO / HZG / DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-DO-20120731 / I:(DE-H253)HZG-20120731 /
                      I:(DE-H253)HAS-User-20120731},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-H253)D-D3-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000363193800011},
      pubmed       = {pmid:26418174},
      doi          = {10.1039/C5CP03557K},
      url          = {https://bib-pubdb1.desy.de/record/293591},
}