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000293591 1001_ $$0P:(DE-H253)PIP1008662$$aKarimi, Fahim$$b0$$eCorresponding author
000293591 245__ $$aStructural and kinetic investigation of the hydride composite $\mathrm{Ca(BH_{4})_{2} + MgH_2}$ system doped with $\mathrm{NbF_5}$ for solid-state hydrogen storage
000293591 260__ $$aCambridge$$bRSC Publ.$$c2015
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000293591 520__ $$aDesigning safe, compact and high capacity hydrogen storage systems is the key step towards introducing a pollutant free hydrogen technology into a broad field of applications. Due to the chemical bonds of hydrogen–metal atoms, metal hydrides provide high energy density in safe hydrogen storage media. Reactive hydride composites (RHCs) are a promising class of high capacity solid state hydrogen storage systems. Ca(BH$_4$)$_2$ + MgH$_2$ with a hydrogen content of 8.4 wt% is one of the most promising members of the RHCs. However, its relatively high desorption temperature of ∼350 °C is a major drawback to meeting the requirements for practical application. In this work, by using NbF5 as an additive, the dehydrogenation temperature of this RHC was significantly decreased. To elucidate the role of NbF5 in enhancing the desorption properties of the Ca(BH$_4$)$_2$ + MgH$_2$ (Ca-RHC), a comprehensive investigation was carried out via manometric measurements, mass spectrometry, Differential Scanning Calorimetry (DSC), in situ Synchrotron Radiation-Powder X-ray Diffraction (SR-PXD), X-ray Absorption Spectroscopy (XAS), Anomalous Small-Angle X-ray Scattering (ASAXS), Scanning and Transmission Electron Microscopy (SEM, TEM) and Nuclear Magnetic Resonance (NMR) techniques.
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000293591 7001_ $$aKlaus Pranzas, P.$$b1
000293591 7001_ $$0P:(DE-H253)PIP1010848$$aPistidda, Claudio$$b2
000293591 7001_ $$aPuszkiel, Julián A.$$b3
000293591 7001_ $$aMilanese, Chiara$$b4
000293591 7001_ $$0P:(DE-H253)PIP1005990$$aVainio, Ulla$$b5
000293591 7001_ $$0P:(DE-H253)PIP1023987$$aPaskevicius, Mark$$b6
000293591 7001_ $$aEmmler, Thomas$$b7
000293591 7001_ $$0P:(DE-H253)PIP1025196$$aSantoru, Antonio$$b8
000293591 7001_ $$aUtke, Rapee$$b9
000293591 7001_ $$0P:(DE-H253)PIP1007498$$aTolkiehn, Martin$$b10$$udesy
000293591 7001_ $$aMinella, Christian B.$$b11
000293591 7001_ $$0P:(DE-H253)PIP1020732$$aChaudhary, Anna-Lisa$$b12
000293591 7001_ $$0P:(DE-H253)PIP1024238$$aBoerries, Stefan$$b13
000293591 7001_ $$aBuckley, Craig E.$$b14
000293591 7001_ $$aEnzo, Stefano$$b15
000293591 7001_ $$0P:(DE-H253)PIP1006650$$aSchreyer, Andreas$$b16
000293591 7001_ $$aKlassen, Thomas$$b17
000293591 7001_ $$0P:(DE-H253)PIP1009603$$aDornheim, Martin$$b18
000293591 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/C5CP03557K$$gVol. 17, no. 41, p. 27328 - 27342$$n41$$p27328 - 27342$$tPhysical chemistry, chemical physics$$v17$$x1463-9084$$y2015
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