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@ARTICLE{Busch:293590,
      author       = {Busch, Nina and Jepsen, Julian and Pistidda, Claudio and
                      Puszkiel, Julián A. and Karimi, Fahim and Milanese, Chiara
                      and Tolkiehn, Martin and Chaudhary, Anna-Lisa and Klassen,
                      Thomas and Dornheim, Martin},
      title        = {{I}nfluence of milling parameters on the sorption
                      properties of the $\mathrm{{L}i{H}–{M}g{B}_2}$ system
                      doped with $\mathrm{{T}i{C}l_3}$},
      journal      = {Journal of alloys and compounds},
      volume       = {645},
      issn         = {0925-8388},
      address      = {Lausanne},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2016-00653},
      pages        = {S299 - S303},
      year         = {2015},
      note         = {(c) Elsevier B.V.},
      abstract     = {Hydrogen sorption properties of the LiH–MgB$_2$ system
                      doped with TiCl$_3$ were investigated with respect to
                      milling conditions (milling times, ball to powder (BTP)
                      ratios, rotation velocities and degrees of filling) to form
                      the reactive hydride composite (RHC) LiBH$_4$–MgH$_2$. A
                      heuristic model was applied to approximate the energy
                      transfer from the mill to the powders. These results were
                      linked to experimentally obtained quantities such as
                      crystallite size, specific surface area (SSA) and
                      homogeneity of the samples, using X-ray diffraction (XRD),
                      the Brunauer–Emmett–Teller (BET) method and scanning
                      electron microscopy (SEM), respectively. The results show
                      that at approximately 20 kJ g−1 there are no further
                      benefits to the system with an increase in energy transfer.
                      This optimum energy transfer value indicates that a plateau
                      was reached for MgB$_2$ crystallite size therefore the there
                      was also no improvement of reaction kinetics due to no
                      change in crystallite size. Therefore, this study shows that
                      an optimum energy transfer value was reached for the
                      LiH–MgB$_2$ system doped with TiCl$_3$.},
      cin          = {FS-DO / DOOR},
      ddc          = {670},
      cid          = {I:(DE-H253)FS-DO-20120731 / I:(DE-H253)HAS-User-20120731},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-H253)D-D3-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000360404100069},
      doi          = {10.1016/j.jallcom.2014.12.187},
      url          = {https://bib-pubdb1.desy.de/record/293590},
}