% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Puszkiel:293230,
      author       = {Puszkiel, J. A. and Gennari, F. C. and Larochette, P.
                      Arneodo and Ramallo-López, J. M. and Vainio, U. and Karimi,
                      F. and Pranzas, P. K. and Troiani, H. and Pistidda, C. and
                      Jepsen, J. and Tolkiehn, M. and Welter, E. and Klassen, T.
                      and Bellosta von Colbe, J. and Dornheim, M.},
      title        = {{E}ffect of {F}e additive on the
                      hydrogenation-dehydrogenation properties of
                      $\mathrm{2{L}i{H} + {M}g{B}_{2}/2{L}i{BH}_{4} + {M}g{H}_{2}}$
                      system},
      journal      = {Journal of power sources},
      volume       = {284},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2016-00386},
      pages        = {606 - 616},
      year         = {2015},
      note         = {(c) Elsevier B.V.},
      abstract     = {Lithium reactive hydride composite 2LiBH$_{4}$ + MgH$_{2}$
                      (Li-RHC) has been lately investigated owing to its potential
                      as hydrogen storage medium for mobile applications. However,
                      the main problem associated with this material is its
                      sluggish kinetic behavior. Thus, aiming to improve the
                      kinetic properties, in the present work the effect of the
                      addition of Fe to Li-RHC is investigated. The addition of Fe
                      lowers the starting decomposition temperature of Li-RHC
                      about 30 °C and leads to a considerably faster isothermal
                      dehydrogenation rate during the first hydrogen sorption
                      cycle. Upon hydrogenation, MgH$_{2}$ and LiBH$_{4}$ are
                      formed whereas Fe appears not to take part in any reaction.
                      Upon the first dehydrogenation, the formation of
                      nanocrystalline, well distributed FeB reduces the overall
                      hydrogen storage capacity of the system. Throughout cycling,
                      the agglomeration of FeB particles causes a kinetic
                      deterioration. An analysis of the hydrogen kinetic mechanism
                      during cycling shows that the hydrogenation and
                      dehydrogenation behavior is influenced by the activity of
                      FeB as heterogeneous nucleation center for MgB$_{2}$ and its
                      non-homogenous distribution in the Li-RHC matrix.},
      cin          = {FS-PEX},
      ddc          = {620},
      cid          = {I:(DE-H253)FS-PEX-20130206},
      pnm          = {6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621)},
      pid          = {G:(DE-HGF)POF3-6213},
      experiment   = {EXP:(DE-H253)D-A1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000354140700074},
      doi          = {10.1016/j.jpowsour.2015.02.153},
      url          = {https://bib-pubdb1.desy.de/record/293230},
}