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@ARTICLE{Solozhenko:289178,
author = {Solozhenko, Vladimir and Kurakevych, Oleksandr},
title = {{E}quilibrium p-{T} {P}hase {D}iagram of {B}oron:
{E}xperimental {S}tudy and {T}hermodynamic {A}nalysis},
journal = {Scientific reports},
volume = {3},
issn = {2045-2322},
address = {London},
publisher = {Nature Publishing Group},
reportid = {PUBDB-2015-05293},
pages = {2351},
year = {2013},
abstract = {Solid-state phase transformations and melting of
high-purity crystalline boron have been in situ and ex situ
studied at pressures to 20 GPa in the 1500–2500 K
temperature range where diffusion processes become fast and
lead to formation of thermodynamically stable phases. The
equilibrium phase diagram of boron has been constructed
based on thermodynamic analysis of experimental and
literature data. The high-temperature part of the diagram
contains p-T domains of thermodynamic stability of
rhombohedral β-B$_{106}$, orthorhombic γ-B$_{28}$,
pseudo-cubic (tetragonal) t'-B$_{52}$, and liquid boron (L).
The positions of two triple points have been experimentally
estimated, i.e. β–t'–L at ~ 8.0 GPa and ~ 2490 K;
and β–γ–t' at ~ 9.6 GPa and ~ 2230 K. Finally, the
proposed phase diagram explains all thermodynamic aspects of
boron allotropy and significantly improves our understanding
of the fifth element.},
cin = {DOOR},
ddc = {000},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {6G3 - PETRA III (POF3-622) / FS-Proposal: I-20090007 EC
(I-20090007-EC) / FS-Proposal: I-20120445 EC
(I-20120445-EC)},
pid = {G:(DE-HGF)POF3-6G3 / G:(DE-H253)I-20090007-EC /
G:(DE-H253)I-20120445-EC},
experiment = {EXP:(DE-H253)D-F2.1-20150101 /
EXP:(DE-H253)P-P02.2-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000322698700001},
pubmed = {pmid:23912523},
doi = {10.1038/srep02351},
url = {https://bib-pubdb1.desy.de/record/289178},
}