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| Home > Publications database > Thermoelastic equation of state of boron suboxide $\mathrm{B_{6}O}$ up to 6 GPa and 2700 K: Simplified Anderson-Grüneisen model and thermodynamic consistency > print |
| Home > Publications database > Thermoelastic equation of state of boron suboxide $\mathrm{B_{6}O}$ up to 6 GPa and 2700 K: Simplified Anderson-Grüneisen model and thermodynamic consistency > print |
| 001 | 289176 | ||
| 005 | 20211114025634.0 | ||
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| 100 | 1 | _ | |a Kurakevych, Oleksandr |0 P:(DE-H253)PIP1011677 |b 0 |
| 245 | _ | _ | |a Thermoelastic equation of state of boron suboxide $\mathrm{B_{6}O}$ up to 6 GPa and 2700 K: Simplified Anderson-Grüneisen model and thermodynamic consistency |
| 260 | _ | _ | |a New York, NY |c 2014 |b Allerton Press |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 500 | _ | _ | |a (c) Allerton Press, Inc. the arxiv v1 version matches with the post referee version. |
| 520 | _ | _ | |a The p-V-T equation of state of superhard boron suboxide $B_{6}O$ has been measured up to 6 GPa and 2700 K using multianvil technique and synchrotron X-ray diffraction. To fit the experimental data, the theoretical p-V-T equation of state has been derived in approximation of the constant value of the Anderson-Grüneisen parameter $\delta$$_{T}$. Bulk modulus B$_{0}$ =181 GPa and its first pressure derivative $B_{0}$$^\prime$ = 6 at 300 K; two parameters describing thermal expansion at 0.1 MPa, i.e., a = 1.4 × $10^{−5} K^{−1}$ and b = 5 × $10^{−9} K^{−2}$ as well as $\delta$$_{T}$ = 6 have been included in the model. The good agreement between fitted and experimental isobars has been achieved to the absolute volume changes up to 5% as compared to the volume at standard conditions, V$_{0}$. The fitted thermal expansion at 0.1 MPa well consistent with the experimental data as well as with ambient-pressure heat capacity c$_{p}$ , bulk modulus B$_{0}$ and $\delta$$_{T}$ describing its evolution with volume and temperature have been discussed. The fitted value of Grüneisen parameter $\gamma$ = 0.85 in agreement with previous empiric estimations for $B_{6}O$ and experimental values for other boron-rich solids has been reported. |
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| 700 | 1 | _ | |a Solozhenko, Vladimir |0 P:(DE-H253)PIP1008160 |b 1 |e Corresponding author |
| 773 | _ | _ | |a 10.3103/S1063457614040054 |g Vol. 36, no. 4, p. 270 - 278 |0 PERI:(DE-600)2316057-3 |n 4 |p 270 - 278 |t Journal of superhard materials |v 36 |y 2014 |x 1934-9408 |
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