TY  - JOUR
AU  - Solozhenko, Vladimir
AU  - Kurakevych, Oleksandr
AU  - LE GODEC, Yann
AU  - Brazhkin, Vadim V.
TI  - Thermodynamically Consistent p – T Phase Diagram of Boron Oxide B<sub>2</sub>O<sub>3</sub> by in Situ Probing and Thermodynamic Analysis
JO  - The journal of physical chemistry  / C
VL  - 119
IS  - 35
SN  - 1932-7455
CY  - Washington, DC
PB  - Soc.
M1  - PUBDB-2015-05290
SP  - 20600 - 20605
PY  - 2015
N1  - (c) American Chemical Society. Post referee full text in progress (embargo 1 year from August 19, 2015).
AB  - Although boron oxide B<sub>2</sub>O<sub>3</sub> is an archetypical glass-forming substance of large industrial and fundamental importance, its phase diagram remains controversial. In the present work, the p–T phase diagram of B<sub>2</sub>O<sub>3</sub> has been constructed based on in situ experimental data up to 8 GPa and 1900 K and thermodynamic analysis. In contrast to the previous studies, the proposed phase diagram represents only thermodynamic equilibria (reversible transformations in experiments) between crystalline (α, β) and liquid states, not influenced by kinetic phenomena.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000360947800043
DO  - DOI:10.1021/acs.jpcc.5b07088
UR  - https://bib-pubdb1.desy.de/record/289175
ER  -