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100 1 _ |a Anspoks, A.
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245 _ _ |a Local structure studies of $\mathrm{SrTi^{16}O_{3}}$ and $\mathrm{SrTi^{18}O_{3}}$
260 _ _ |a Bristol
|c 2014
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500 _ _ |a (c) The Royal Swedish Academy of Sciences
520 _ _ |a In this work we report on the local structure of Ti in SrTi$^{16}$O$_{3}$ (STO16) and SrTi$^{18}$O$_{3}$ (STO18) investigated in the low temperature range (6–300 K) by extended x-ray absorption fine structure and x-ray absorption near edge structure (XANES) spectroscopy at Ti K-edge and by optical second harmonic generation (SHG). By comparing XANES of STO16 and STO18 we have identified the isotopic effect which produces at T < 100K a noticeable difference in the measured mean square relative displacements (MSRD) of Ti–O1 bonds: while STO16 follow the expected Einstein-like behavior, for STO18 we have measured an increase of MSRD values with decreasing temperature. This is an indication of an increasing off-center position of the Ti atoms in the TiO$_{6}$ octahedra.
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700 1 _ |a Bocharov, D.
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700 1 _ |a Purans, J.
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700 1 _ |a Rocca, F.
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700 1 _ |a Sarakovskis, A.
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700 1 _ |a Trepakov, V.
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700 1 _ |a Dejneka, A.
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700 1 _ |a Itoh, M.
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773 _ _ |a 10.1088/0031-8949/89/04/044002
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