Home > Publications database > Local structure studies of $\mathrm{SrTi^{16}O_{3}}$ and $\mathrm{SrTi^{18}O_{3}}$ > print |
001 | 288954 | ||
005 | 20211110132535.0 | ||
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100 | 1 | _ | |a Anspoks, A. |0 P:(DE-H253)PIP1011942 |b 0 |e Corresponding author |
245 | _ | _ | |a Local structure studies of $\mathrm{SrTi^{16}O_{3}}$ and $\mathrm{SrTi^{18}O_{3}}$ |
260 | _ | _ | |a Bristol |c 2014 |b IoP Publ. |
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500 | _ | _ | |a (c) The Royal Swedish Academy of Sciences |
520 | _ | _ | |a In this work we report on the local structure of Ti in SrTi$^{16}$O$_{3}$ (STO16) and SrTi$^{18}$O$_{3}$ (STO18) investigated in the low temperature range (6–300 K) by extended x-ray absorption fine structure and x-ray absorption near edge structure (XANES) spectroscopy at Ti K-edge and by optical second harmonic generation (SHG). By comparing XANES of STO16 and STO18 we have identified the isotopic effect which produces at T < 100K a noticeable difference in the measured mean square relative displacements (MSRD) of Ti–O1 bonds: while STO16 follow the expected Einstein-like behavior, for STO18 we have measured an increase of MSRD values with decreasing temperature. This is an indication of an increasing off-center position of the Ti atoms in the TiO$_{6}$ octahedra. |
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700 | 1 | _ | |a Bocharov, D. |b 1 |
700 | 1 | _ | |a Purans, J. |b 2 |
700 | 1 | _ | |a Rocca, F. |b 3 |
700 | 1 | _ | |a Sarakovskis, A. |b 4 |
700 | 1 | _ | |a Trepakov, V. |b 5 |
700 | 1 | _ | |a Dejneka, A. |b 6 |
700 | 1 | _ | |a Itoh, M. |b 7 |
773 | _ | _ | |a 10.1088/0031-8949/89/04/044002 |g Vol. 89, no. 4, p. 044002 - |0 PERI:(DE-600)1477351-x |n 4 |p 044002 |t Physica scripta |v 89 |y 2014 |x 0031-8949 |
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