001     208873
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024 7 _ |a 1520-8540
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100 1 _ |a Pustovarov, Vladimir
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245 _ _ |a Electronic Properties of undoped $LiBaAlF_6$ Single Crystals: Far-Ultraviolet Optical, Luminescence, and X-Ray Photoelectron Spectroscopy Studies
260 _ _ |a Washington, DC
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520 _ _ |a The electronic structure properties of undoped single crystals of LiBaAlF6 (LBAF) were determined using low-temperature (T=10  K) time-resolved far-ultraviolet (3.7–40 eV) synchrotron radiation spectroscopy, calculations for the spectra of optical functions, and x-ray photoelectron spectroscopy. The bandgap of the investigated compound was found at Eg=12.3  eV, the energy threshold for creation of the unrelaxed excitons at En=1=11.6  eV, and the low-energy fundamental absorption edge at 11.0 eV. The subnanosecond photoluminescence emission band at 6.6 eV in LBAF single crystal is due to radiative valence-core transitions 2p F−→5p Ba2+.
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700 1 _ |a Ogorodnikov, Igor
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700 1 _ |a Omelkov, Sergey
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700 1 _ |a Spassky, Dmitry
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700 1 _ |a Isaenko, Ludmila I.
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773 _ _ |a 10.1364/JOSAB.31.001926
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