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@PHDTHESIS{Skaugen:208324,
author = {Skaugen, Arvid},
othercontributors = {Roehlsberger, Ralf and Rübhausen, Michael},
title = {{E}xchange {I}nteractions and {I}nduced ${E}u^{3+}$
{M}agnetic {O}rder in ${RM}n{O}_{3}$ {I}nvestigated {U}sing
{R}esonant {X}-ray {D}iffraction},
issn = {1435-8085},
school = {Universität Hamburg},
type = {Dissertation},
publisher = {Verlag Deutsches Elektronen-Synchrotron},
reportid = {PUBDB-2015-01676, DESY-THESIS-2015-011},
series = {DESY-THESIS},
pages = {137},
year = {2015},
note = {Dissertation, Universität Hamburg, 2015},
abstract = {The so-called multiferroics, materials that concomitantly
exhibit more than one ferroic order, have in recent years
attracted much attention owing totheir possible applications
in high density data storage, high sensitivity ac magnetic
field sensors and novel spintronic devices. In particular,
multifer-roics with strong magnetoelectric coupling are more
attractive. Among such multiferroics, an interesting special
class is the orthorhombic manganiteswith perovskite
structure. In these compounds, frustration serves to
destabilize ordinary ferromagnetic or antiferromagnetic
ordering, giving rise to richphase diagrams due to several
competing magnetic interactions. Interactions between strong
rare earth magnetic moments and weaker transition
metalmoments add another level of complexity, as well as
interest. The current dissertation presents results obtained
investigating the mag-netic structure responsible for
ferroelectricity in a few selected multiferroic compounds,
using x-ray resonant magnetic scattering (XRMS). In
particular,single crystals of Eu1−xYxMnO3 have been
studied at low temperatures and in high magnetic fields.
This series of compounds is similar in structure tothe
heavily studied RMnO3 (R=Tb,Gd,Dy), only without rare earth
magnetism. The novel technique of full polarization analysis
has been used todetermine the complicated cycloidal Mn
magnetic ordering, and additional components due to the
Dzyaloshinskii-Moriya interactions have been iden-tified. In
the compound Eu0.8Y0.2MnO3, two coexisting multiferroic
phases were observed, and a magnetoelectric coupling between
the two was established. Moreover, magnetic order of the
formally non-magnetic rare earth ion Eu3+ was observed in
the same compound. It has been concluded toresult from a Van
Vleck type excitation of the J = 0 ground state due to the
symmetry-breaking internal exchange field from the Mn
magnetic moments.In addition, this dissertation reports on
high field investigations of the complex low-temperature
phases of GdMnO3 as well as high energy non-resonant
scattering studies of TbMnO3. In the case of TbMnO3, the
simple high energy magnetic cross section allowed for direct
determination of spincomponents in the ferroelectric phase.
In the case of GdMnO3, the first high field XRMS
investigation below the Gd ordering temperature was
performed, revealing an important role of the symmetric
exchange interaction between the Gd and Mn subsystems for
stabilizing ferroelectricity in the compound.},
keywords = {Dissertation (GND)},
cin = {FS-PE},
cid = {I:(DE-H253)FS-PE-20120731},
pnm = {6212 - Quantum Condensed Matter: Magnetism,
Superconductivity (POF3-621) / 6G3 - PETRA III (POF3-622) /
PHGS, VH-GS-500 - PIER Helmholtz Graduate School
$(2015_IFV-VH-GS-500)$},
pid = {G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6G3 /
$G:(DE-HGF)2015_IFV-VH-GS-500$},
experiment = {EXP:(DE-H253)P-P09-20150101 / EXP:(DE-H253)P-P07-20150101},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
doi = {10.3204/DESY-THESIS-2015-011},
url = {https://bib-pubdb1.desy.de/record/208324},
}