Home > Publications database > Depth Profiling of Element Concentrations in Stratified Materials by Confocal Microbeam X-ray Fluorescence Spectrometry with Polychromatic Excitation > print

001     207305
005     20250730145759.0
024 7 _ |a 10.1021/ac502897g
|2 doi
024 7 _ |a 0003-2700
|2 ISSN
024 7 _ |a 0096-4484
|2 ISSN
024 7 _ |a 1520-6882
|2 ISSN
024 7 _ |a WOS:000345263300042
|2 WOS
024 7 _ |a pmid:25307861
|2 pmid
024 7 _ |a altmetric:2924821
|2 altmetric
024 7 _ |a openalex:W2330488944
|2 openalex
037 _ _ |a PUBDB-2015-01288
082 _ _ |a 540
100 1 _ |0 P:(DE-H253)PIP1011731
|a Wrobel, Pawel
|b 0
|e Corresponding Author
245 _ _ |a Depth Profiling of Element Concentrations in Stratified Materials by Confocal Microbeam X-ray Fluorescence Spectrometry with Polychromatic Excitation
260 _ _ |a Columbus, Ohio
|b American Chemical Society
|c 2014
336 7 _ |0 0
|2 EndNote
|a Journal Article
336 7 _ |2 DRIVER
|a article
336 7 _ |0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
|a Journal Article
|b journal
|m journal
|s 1444917883_4848
336 7 _ |2 BibTeX
|a ARTICLE
500 _ _ |a (c) American Chemical Society. Post referee full text in progress.
520 _ _ |a The confocal microbeam X-ray fluorescence technique is a well-established analytical tool that is widely used for qualitative and quantitative analysis of stratified materials. There are several different reconstruction methods dedicated to this type of samples. However, these methods are applicable with monochromatic excitation only. The full description of matrix effects and geometrical effects for polychromatic X-ray photons in confocal geometry is a demanding task. In the present paper, this problem was overcome by the use of effective energy approximation. The reduction of the whole energy dimension into one effective value eliminates the necessity of integration over the primary beam energy range for a number of basic parameters. This simplification is attainable without loss of the accuracy of analysis. The proposed approach was validated by applying it to the reconstruction of element concentration depth profiles of stratified standard samples measured with tabletop confocal microbeam X-ray fluorescence setup and by comparing the obtained results of two independent algorithms.
536 _ _ |0 G:(DE-H253)POF2-L-20130405
|f POF II
|x 0
|c POF2-54G13
|a DORIS Beamline L (POF2-54G13)
588 _ _ |a Dataset connected to CrossRef, bib-pubdb1.desy.de
693 _ _ |0 EXP:(DE-H253)D-L-20150101
|1 EXP:(DE-H253)DORISIII-20150101
|6 EXP:(DE-H253)D-L-20150101
|a DORIS III
|f DORIS Beamline L
|x 0
700 1 _ |0 P:(DE-H253)PIP1011846
|a Wegrzynek, Dariusz
|b 1
700 1 _ |0 P:(DE-H253)PIP1008366
|a Czyzycki, Mateusz
|b 2
|u desy
700 1 _ |0 P:(DE-H253)PIP1007362
|a Lankosz, Marek
|b 3
773 _ _ |0 PERI:(DE-600)1483443-1
|a 10.1021/ac502897g
|g Vol. 86, no. 22, p. 11275 - 11280
|n 22
|p 11275 - 11280
|t Analytical chemistry
|v 86
|x 1520-6882
|y 2014
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.pdf
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.gif?subformat=icon
|x icon
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.jpg?subformat=icon-1440
|x icon-1440
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.jpg?subformat=icon-180
|x icon-180
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.jpg?subformat=icon-640
|x icon-640
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.jpg?subformat=icon-700
|x icon-700
|y Restricted
856 4 _ |u https://bib-pubdb1.desy.de/record/207305/files/10.1021_ac502897g.pdf?subformat=pdfa
|x pdfa
|y Restricted
909 C O |o oai:bib-pubdb1.desy.de:207305
|p VDB
910 1 _ |0 I:(DE-HGF)0
|6 P:(DE-H253)PIP1011731
|a Externes Institut
|b 0
|k >Extern
910 1 _ |0 I:(DE-HGF)0
|6 P:(DE-H253)PIP1011846
|a Externes Institut
|b 1
|k >Extern
910 1 _ |0 I:(DE-588b)2008985-5
|6 P:(DE-H253)PIP1008366
|a Deutsches Elektronen-Synchrotron
|b 2
|k DESY
910 1 _ |0 I:(DE-HGF)0
|6 P:(DE-H253)PIP1007362
|a Externes Institut
|b 3
|k >Extern
913 2 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF3-620
|0 G:(DE-HGF)POF3-621
|2 G:(DE-HGF)POF3-600
|v In-house research on the structure, dynamics and function of matter
|9 G:(DE-HGF)POF3-6215
|x 0
913 1 _ |0 G:(DE-HGF)POF2-54G13
|1 G:(DE-HGF)POF2-540
|2 G:(DE-HGF)POF2-500
|9 G:(DE-H253)POF2-L-20130405
|b Struktur der Materie
|v DORIS III
|x 0
|a DE-H253
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF2
|l Forschung mit Photonen, Neutronen, Ionen
914 1 _ |y 2014
915 _ _ |0 StatID:(DE-HGF)0100
|2 StatID
|a JCR
915 _ _ |0 StatID:(DE-HGF)0110
|2 StatID
|a WoS
|b Science Citation Index
915 _ _ |0 StatID:(DE-HGF)0111
|2 StatID
|a WoS
|b Science Citation Index Expanded
915 _ _ |0 StatID:(DE-HGF)0150
|2 StatID
|a DBCoverage
|b Web of Science Core Collection
915 _ _ |0 StatID:(DE-HGF)0199
|2 StatID
|a DBCoverage
|b Thomson Reuters Master Journal List
915 _ _ |0 StatID:(DE-HGF)0200
|2 StatID
|a DBCoverage
|b SCOPUS
915 _ _ |0 StatID:(DE-HGF)0300
|2 StatID
|a DBCoverage
|b Medline
915 _ _ |0 StatID:(DE-HGF)0310
|2 StatID
|a DBCoverage
|b NCBI Molecular Biology Database
915 _ _ |0 StatID:(DE-HGF)0420
|2 StatID
|a Nationallizenz
915 _ _ |0 StatID:(DE-HGF)1030
|2 StatID
|a DBCoverage
|b Current Contents - Life Sciences
915 _ _ |0 StatID:(DE-HGF)1150
|2 StatID
|a DBCoverage
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |0 StatID:(DE-HGF)9905
|2 StatID
|a IF >= 5
920 1 _ |0 I:(DE-H253)HAS-User-20120731
|k DOOR
|l DOOR-User
|x 0
920 1 _ |0 I:(DE-H253)FS-PE-20120731
|k FS-PE
|l Experimentebetreuung PETRA III
|x 1
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-H253)HAS-User-20120731
980 _ _ |a I:(DE-H253)FS-PE-20120731
980 _ _ |a UNRESTRICTED

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21