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@ARTICLE{Wharmby:207237,
      author       = {Wharmby, Michael and Snoyek, Malte and Rhauderwiek, Timo
                      and Ritter, Knut and Stock, Norbert},
      title        = {{G}roup 13 {M}etal {C}arboxylates: {U}sing {M}olecular
                      {C}lusters {A}s {H}ybrid {B}uilding {U}nits in a {MIL}-53
                      {T}ype {F}ramework},
      journal      = {Crystal growth $\&$ design},
      volume       = {14},
      number       = {10},
      issn         = {1528-7483},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {PUBDB-2015-01220},
      pages        = {5310 - 5317},
      year         = {2014},
      note         = {(c) American Chemical Society. Post referee full text in
                      progress. Embargo for full text 1 year from August 20,
                      2014.},
      abstract     = {Systematic investigation of the reactions of the system
                      AlCl3·6H2O/pyridine-2,4,6-tricarboxylic acid
                      (H3PTC)/pyridine in water yielded two new compounds, both
                      containing the dimeric {AlPTC(μ-OH)(H2O)}22– unit. With
                      long reaction times, the framework compound
                      [Al(μ-OH){AlPTC(μ-OH)(H2O)}2]·2H2O (CAU-16, compound 1)
                      is obtained, the first example of a framework compound with
                      a metal–organic cluster linker, and bearing the MIL-53
                      network. Although the compound does not breathe, as other
                      MIL-53 compounds do, it has a maximum uptake of CO2 of
                      1.76(2) mmol g–1 at 196 K. With shorter reaction times,
                      the molecular compound {Al(HPTC)(μ-OH)(H2O)}2 (2) was
                      prepared, leading to the proposal of a crystallization
                      scheme for the Al3+-pyridine-2,4,6,-tricarboxylic acid
                      system. To determine whether further framework compounds
                      bearing hybrid metal cluster linkers could be prepared,
                      systematic high-throughput investigations of
                      pyridine-2,4,6-tricarboxylic acid in water with Ga3+ and
                      In3+ were undertaken. These yielded two chain-type
                      compounds, GaPTC(H2O)2 (3) and InPTC(H2O)2 (4), with
                      different coordination chemistries. Optimized syntheses for
                      compounds 1, 2, and 4 are reported.},
      cin          = {DOOR},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {PETRA Beamline P08 (POF2-54G14) / MACADEMIA - MOFs as
                      Catalysts and Adsorbents: Discovery and Engineering of
                      Materials for Industrial Applications (228862)},
      pid          = {G:(DE-H253)POF2-P08-20130405 / G:(EU-Grant)228862},
      experiment   = {EXP:(DE-H253)P-P08-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000342609300056},
      doi          = {10.1021/cg501189n},
      url          = {https://bib-pubdb1.desy.de/record/207237},
}