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@ARTICLE{Peters:207129,
author = {Peters, S. and Peredkov, S. and Al-Hada, M. and Neeb, M.
and Eberhardt, W.},
title = {{P}ositive {XPS} {B}inding {E}nergy {S}hift of {S}upported
{C}u{N}-{C}lusters {G}overned by {I}nitial {S}tate
{E}ffects},
journal = {Journal of electron spectroscopy and related phenomena},
volume = {192},
issn = {0368-2048},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PUBDB-2015-01114},
pages = {52 - 54},
year = {2014},
abstract = {An initial state effect is established as origin for the
positive 2p core electron binding energy shift found for
CuN-clusters supported by a thin silica layer of a p-doped
Si(1 0 0) wafer. Using the concept of the Auger parameter
and taking into account the usually neglected Coulomb
correlation shift in the Auger final state (M4,5M4,5) it is
shown that the initial state shift is comparable to the
measured XPS shift while the final state relaxation shift
contributes only marginally to the binding energy shift. The
cluster results differ from the negative surface core-level
shift of crystalline copper which has been explained in
terms of a final state relaxation effect.},
cin = {FS-PS / DOOR},
ddc = {620},
cid = {I:(DE-H253)FS-PS-20131107 / I:(DE-H253)HAS-User-20120731},
pnm = {FS In-house research / theory (POF2-544)},
pid = {G:(DE-H253)POF2-(In-house)-20130405},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000335546500009},
doi = {10.1016/j.elspec.2014.01.011},
url = {https://bib-pubdb1.desy.de/record/207129},
}