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@ARTICLE{Palumbiny:206546,
      author       = {Palumbiny, Claudia Maria and Heller, Christoph and
                      Schaffer, Christoph and Koerstgens, Volker and Santoro,
                      Gonzalo and Roth, Stephan and Mueller-Buschbaum, Peter},
      title        = {{M}olecular {R}eorientation and {S}tructural {C}hanges in
                      {C}osolvent-{T}reated {H}ighly {C}onductive {PEDOT}:{PSS}
                      {E}lectrodes for {F}lexible {I}ndium {T}in {O}xide-{F}ree
                      {O}rganic {E}lectronics},
      journal      = {The journal of physical chemistry / C},
      volume       = {118},
      number       = {25},
      issn         = {1932-7447},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PUBDB-2015-01010},
      pages        = {13598 - 13606},
      year         = {2014},
      note         = {(c) American Chemical Society. Post referee full text in
                      progress. Embargo full text 1 year from June 1, 2014.},
      abstract     = {Cosolvent addition of glycerol (G) and the use of the
                      cosolvent ethylene glycol (EG) increase the conductivity of
                      poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate)
                      (PEDOT:PSS) films to values on the order of indium tin oxide
                      conductivity. The underlying morphological changes are
                      probed via scanning electron microscopy as well as advanced
                      scattering techniques microfocused grazing incidence small-
                      and wide-angle X-ray scattering. The enhancement in
                      conductivity is ascribed to fundamental morphological
                      changes and molecular reorientation within crystalline
                      domains. Thereby, the conductivity enhancement is directly
                      correlated to domain ruptures toward smaller and more
                      densely packed PEDOT domains together with an enhanced
                      crystallinity, the removal of PSS molecules, and moreover a
                      reorientation of the conjugated PEDOT molecules. The latter
                      is reported and quantified here for PEDOT:PSS films for the
                      first time.},
      cin          = {DOOR / FS-PE},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PE-20120731},
      pnm          = {PETRA Beamline P03 (POF2-54G14) / FS-Proposal: I-20120602
                      EC (I-20120602-EC)},
      pid          = {G:(DE-H253)POF2-P03-20130405 / G:(DE-H253)I-20120602-EC},
      experiment   = {EXP:(DE-H253)P-P03-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000338184300030},
      doi          = {10.1021/jp501540y},
      url          = {https://bib-pubdb1.desy.de/record/206546},
}