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@ARTICLE{Popov:206296,
author = {Popov, V. V. and Zubavichus, Ya. V. and Menushenkov, Alexey
and Yaroslavtsev, A. A. and Petrunin, V. F. and Korovin, S.
A. and Trofimova, N. N. and Kulik, E. S.},
title = {{S}hort- and long-range order balance in nanocrystalline
${G}d_{2}{Z}r_{2}{O}_{7}$ powders with a fluorite-pyrochlore
structure},
journal = {Russian journal of inorganic chemistry},
volume = {59},
number = {4},
issn = {1531-8613},
address = {Moscow},
publisher = {MAIK Nauka/Interperiodica Publ.},
reportid = {PUBDB-2015-00801},
pages = {279 - 285},
year = {2014},
note = {(c) leiades Publishing, Ltd. Post referee full text in
progress.},
abstract = {A series of nanocrystalline $Gd_{2}Zr_{2}O_{7}$ powders has
been studied using a combination of X-ray diffraction and
X-ray spectroscopy with synchrotron radiation. It has been
shown that isothermal annealing of an X-ray amorphous mixed
hydroxide first leads to the formation of an oxide
nanomaterial with a defect fluorite structure and clearly
pronounced nonequivalence of the local environment of the
$Gd^{3+} and Zr^{4+}$ ions. Increasing heat treatment
temperature results in initiation and growth of nanodomains
with pyrochlore-type superstructure ordering of cations
inside bulkier crystallites of defect fluorite. To
adequately describe the evolution of the real
nanocrystalline structure of gadolinium zirconate, a
combination of X-ray structural methods sensitive to the
averaged crystal structure and local atomic structure should
be used.},
cin = {FS-PE},
ddc = {540},
cid = {I:(DE-H253)FS-PE-20120731},
pnm = {PETRA Beamline P02.1 (POF2-54G14) / FS-Proposal: I-20120512
(I-20120512)},
pid = {G:(DE-H253)POF2-P02.1-20140410 / G:(DE-H253)I-20120512},
experiment = {EXP:(DE-H253)P-P02.1-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000334500100001},
doi = {10.1134/S0036023614040147},
url = {https://bib-pubdb1.desy.de/record/206296},
}